Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis

KY Wang, J Zhang, YC Hsu, H Lin, Z Han… - Chemical …, 2023 - ACS Publications
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

A comprehensive review of the mechanisms and efficiency of underground hydrogen storage

SR Thiyagarajan, H Emadi, A Hussain… - Journal of Energy …, 2022 - Elsevier
Abstract Underground Hydrogen Storage can be proven very beneficial for recurring supply
of clean energy throughout the world. This paper reviews different challenges like microbial …

Underground hydrogen storage: A comprehensive review

D Zivar, S Kumar, J Foroozesh - International journal of hydrogen energy, 2021 - Elsevier
Increased emissions of greenhouse gasses into the atmosphere has adversely been
contributing to global warming as a result of burning fossil fuels. Therefore, the energy …

Second and outer coordination sphere effects in nitrogenase, hydrogenase, formate dehydrogenase, and CO dehydrogenase

ST Stripp, BR Duffus, V Fourmond, C Léger… - Chemical …, 2022 - ACS Publications
Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …

Mechanisms of nickel-catalyzed cross-coupling reactions

JB Diccianni, T Diao - Trends in Chemistry, 2019 - cell.com
Advances in nickel-catalyzed cross-coupling reactions have expanded the chemical space
of accessible structures and enabled new synthetic disconnections. The unique properties of …

Microbial oxidation of atmospheric trace gases

C Greening, R Grinter - Nature Reviews Microbiology, 2022 - nature.com
The atmosphere has recently been recognized as a major source of energy sustaining life.
Diverse aerobic bacteria oxidize the three most abundant reduced trace gases in the …

Hydrogenase enzymes and their synthetic models: the role of metal hydrides

D Schilter, JM Camara, MT Huynh… - Chemical …, 2016 - ACS Publications
Hydrogenase enzymes efficiently process H2 and protons at organometallic FeFe, NiFe, or
Fe active sites. Synthetic modeling of the many H2ase states has provided insight into …

Hydrogenases

W Lubitz, H Ogata, O Rudiger, E Reijerse - Chemical reviews, 2014 - ACS Publications
The reaction takes place at a specialized metal center that dramatically increases the acidity
of H2 and leads to a heterolytic splitting of the molecule which is strongly accelerated by the …

[HTML][HTML] Structural basis for bacterial energy extraction from atmospheric hydrogen

R Grinter, A Kropp, H Venugopal, M Senger, J Badley… - Nature, 2023 - nature.com
Diverse aerobic bacteria use atmospheric H2 as an energy source for growth and survival.
This globally significant process regulates the composition of the atmosphere, enhances soil …