Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas
reactions to form a wide range of Markovnikov-selective olefin radical …

The combination of photoredox and transition metal catalysis, which is termed
metallaphotoredox catalysis, is a powerful platform for building complex molecules under …

The transition-metal-catalysed cross-coupling reaction has established itself as one of the
most reliable and practical synthetic tools for the efficient construction of carbon …

Free radicals are important subjects in organic, bioorganic, medicinal, material, and
atmospheric chemistries. Synthetic utilities of free radicals have been well-accomplished in …

A practical silver‐catalyzed decarboxylative allylation of α, α‐difluoroarylacetic acids with
allyl sulfones is described, which provides a variety of β, β‐difluorinated alkenes in good …

Reserpine (1) is one of the lipid-soluble indole alkaloids sharing the yohimbine pentacyclic
skeleton. Pharmacological studies have revealed that reserpine is a central nervous system …

This tutorial review aims at presenting recent contributions dealing with organic chemistry of
organophosphorus radicals. The first part briefly lays out the physical organic background of …

C C bond formation is one of the most important synthetic steps in the construction of
organic molecules. In the last few years it has been increasingly achieved by radical …

The total synthesis of the title compounds has been accomplished. The key step involves the
kinetic stereoselective conversion of 19→ 20. The synthesis of 20 represents for the first time …

For many years, free radical species have been known to be intermediates in a large
number of chemical reactions and have been credited to produce polymers of industrial …