Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W Jing, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Single‐atom catalysis for carbon neutrality

L Wang, D Wang, Y Li - Carbon Energy, 2022 - Wiley Online Library
Currently, more than 86% of global energy consumption is still mainly dependent on
traditional fossil fuels, which causes resource scarcity and even emission of high amounts of …

Size of cerium dioxide support nanocrystals dictates reactivity of highly dispersed palladium catalysts

V Muravev, A Parastaev, Y van den Bosch, B Ligt… - Science, 2023 - science.org
The catalytic performance of heterogeneous catalysts can be tuned by modulation of the
size and structure of supported transition metals, which are typically regarded as the active …

Single-atom catalysts based on the metal–oxide interaction

R Lang, X Du, Y Huang, X Jiang, Q Zhang… - Chemical …, 2020 - ACS Publications
Metal atoms dispersed on the oxide supports constitute a large category of single-atom
catalysts. In this review, oxide supported single-atom catalysts are discussed about their …

Advances in heterogeneous single-cluster catalysis

X Li, S Mitchell, Y Fang, J Li, J Perez-Ramirez… - Nature Reviews …, 2023 - nature.com
Heterogeneous single-cluster catalysts (SCCs) comprising atomically precise and isolated
metal clusters stabilized on appropriately chosen supports offer exciting prospects for …

General design concept for single‐atom catalysts toward heterogeneous catalysis

W Guo, Z Wang, X Wang, Y Wu - Advanced Materials, 2021 - Wiley Online Library
As a new and popular material, single‐atom catalysts (SACs) exhibit excellent activity,
selectivity, and stability for numerous important reactions, and show great potential in …

Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

Computational methods in heterogeneous catalysis

BWJ Chen, L Xu, M Mavrikakis - Chemical Reviews, 2020 - ACS Publications
The unprecedented ability of computations to probe atomic-level details of catalytic systems
holds immense promise for the fundamentals-based bottom-up design of novel …

Formation of active sites on transition metals through reaction-driven migration of surface atoms

L Xu, KG Papanikolaou, BAJ Lechner, L Je… - Science, 2023 - science.org
Adopting low-index single-crystal surfaces as models for metal nanoparticle catalysts has
been questioned by the experimental findings of adsorbate-induced formation of …

Well-defined materials for heterogeneous catalysis: from nanoparticles to isolated single-atom sites

Z Li, S Ji, Y Liu, X Cao, S Tian, Y Chen, Z Niu… - Chemical …, 2019 - ACS Publications
The use of well-defined materials in heterogeneous catalysis will open up numerous new
opportunities for the development of advanced catalysts to address the global challenges in …