Recent advances in polyoxometalate-catalyzed reactions
SS Wang, GY Yang - Chemical reviews, 2015 - ACS Publications
Polyoxometalates (POMs) are composed of cations and polyanion clusters 1 with structural
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …
[HTML][HTML] Artificial photosynthesis: molecular systems for catalytic water oxidation
The sustainable production of clean energy constitutes one of the most important scientific
challenges of the 21st century. Currently, the major part of the global energy supply is …
challenges of the 21st century. Currently, the major part of the global energy supply is …
Identifying intermediates in electrocatalytic water oxidation with a manganese corrole complex
X Li, XP Zhang, M Guo, B Lv, K Guo, X Jin… - Journal of the …, 2021 - ACS Publications
Water nucleophilic attack (WNA) on high-valent terminal Mn-oxo species is proposed for O–
O bond formation in natural and artificial water oxidation. Herein, we report an …
O bond formation in natural and artificial water oxidation. Herein, we report an …
Introducing Water‐Network‐Assisted Proton Transfer for Boosted Electrocatalytic Hydrogen Evolution with Cobalt Corrole
X Li, B Lv, XP Zhang, X Jin, K Guo… - Angewandte Chemie …, 2022 - Wiley Online Library
Proton transfer is vital for many biological and chemical reactions. Hydrogen‐bonded water‐
containing networks are often found in enzymes to assist proton transfer, but similar strategy …
containing networks are often found in enzymes to assist proton transfer, but similar strategy …
Molecular chromophore–catalyst assemblies for solar fuel applications
As the world's population increases, the US Department of Energy has estimated that energy
consumption will increase with it, increasing from 5.7× 1020 J in 2012 to 8.1× 1020 J in …
consumption will increase with it, increasing from 5.7× 1020 J in 2012 to 8.1× 1020 J in …
Biochemistry and theory of proton-coupled electron transfer
Through incremental change, Nature reworks and repurposes its functional machinery. In
this way, proteins that photochemically repair DNA by moving protons and electrons have a …
this way, proteins that photochemically repair DNA by moving protons and electrons have a …
Efficient water oxidation catalysts based on readily available iron coordination complexes
Water oxidation catalysis constitutes the bottleneck for the development of energy-
conversion schemes based on sunlight. To date, state-of-the-art homogeneous water …
conversion schemes based on sunlight. To date, state-of-the-art homogeneous water …
Proton-coupled electron transfer
DR Weinberg, CJ Gagliardi, JF Hull, CF Murphy… - Chemical …, 2012 - ACS Publications
An initial review (PCET1) on proton-coupled electron transfer (PCET) by Huynh and Meyer
appeared in Chemical Reviews in 2007.(1) This is a follow-up on the original. It was …
appeared in Chemical Reviews in 2007.(1) This is a follow-up on the original. It was …
O–O bond formation mechanisms during the oxygen evolution reaction over synthetic molecular catalysts
XP Zhang, HY Wang, H Zheng, W Zhang… - Chinese Journal of …, 2021 - Elsevier
Water oxidation is one of the most important reactions in natural and artificial energy
conversion schemes. In nature, solar energy is converted to chemical energy via water …
conversion schemes. In nature, solar energy is converted to chemical energy via water …
Electrocatalytic water oxidation with a copper (II) polypeptide complex
A self-assembly-formed triglycylglycine macrocyclic ligand (TGG4–) complex of Cu
(II),[(TGG4–) CuII–OH2] 2–, efficiently catalyzes water oxidation in a phosphate buffer at pH …
(II),[(TGG4–) CuII–OH2] 2–, efficiently catalyzes water oxidation in a phosphate buffer at pH …