Porous organic cages for gas separations

W Wang, K Su, D Yuan - Materials Chemistry Frontiers, 2023 - pubs.rsc.org
Gases have played a crucial role in various industries, spanning from manufacturing and
medicine to electronics. In these industries, the attainment of pure gases through effective …

Porosity as a design element for developing catalytic molecular materials for electrochemical and photochemical carbon dioxide reduction

P De La Torre, L An, CJ Chang - Advanced Materials, 2023 - Wiley Online Library
The catalytic reduction of carbon dioxide (CO2) using sustainable energy inputs is a
promising strategy for upcycling of atmospheric carbon into value‐added chemical products …

Synergistic Porosity and Charge Effects in a Supramolecular Porphyrin Cage Promote Efficient Photocatalytic CO2 Reduction**

L An, P De La Torre, PT Smith… - Angewandte Chemie …, 2023 - Wiley Online Library
We present a supramolecular approach to catalyzing photochemical CO2 reduction through
second‐sphere porosity and charge effects. An iron porphyrin box (PB) bearing 24 cationic …

Porous organic compounds–small pores on the rise

T Kunde, T Pausch, BM Schmidt - European Journal of Organic …, 2021 - Wiley Online Library
Porous materials are important for various energy‐related technologies such as catalysis
and separation. While porous organic cage compounds are a rather recent addition to the …

Leveraging Halogen Interactions for a Supramolecular Nanotube

S Fisher, LA Malaspina… - … A European Journal, 2024 - Wiley Online Library
We demonstrate the formation of supramolecular nanotubes from molecular triangles in a
single crystal by balancing the hydrogen bonds and halogen interactions between individual …

Kinetic Trapping of Rylene Diimide Covalent Organic Cages

S Fisher, HH Huang, L Sokoliuk, A Prescimone, O Fuhr… - 2024 - chemrxiv.org
Formation of imine organic cages relies on error-correction of dynamic covalent chemistry.
Here, we demonstrate kinetically-trapped rylene diimide cages formed in high yields and we …