Rare earth elements: Mendeleev's bane, modern marvels

T Cheisson, EJ Schelter - Science, 2019 - science.org
The rare earths (REs) are a family of 17 elements that exhibit pronounced chemical
similarities as a group, while individually expressing distinctive and varied electronic …

Coordination chemistry-driven approaches to rare earth element separations

RF Higgins, KP Ruoff, A Kumar… - Accounts of Chemical …, 2022 - ACS Publications
Conspectus Current projections for global mining indicate that unsustainable practices will
cause supply problems for many elements, called critical raw materials, in the next 20 years …

Bridging hydrometallurgy and biochemistry: A protein-based process for recovery and separation of rare earth elements

Z Dong, JA Mattocks, GJP Deblonde, D Hu… - ACS Central …, 2021 - ACS Publications
The extraction and subsequent separation of individual rare earth elements (REEs) from
REE-bearing feedstocks represent a challenging yet essential task for the growth and …

Selective separation of light rare-earth elements by supramolecular encapsulation and precipitation

JG O'Connell-Danes, BT Ngwenya… - Nature …, 2022 - nature.com
Supramolecular chemical strategies for Rare Earth (RE) element separations are emerging
which amplify the small changes in properties across the series to bias selectivity in …

Tetradentate Ligand's Chameleon-Like Behavior Offers Recognition of Specific Lanthanides

S Pramanik, B Li, DM Driscoll… - Journal of the …, 2024 - ACS Publications
The surging demand for high-purity individual lanthanides necessitates the development of
novel and exceptionally selective separation strategies. At the heart of these separation …

Elucidating the speciation of extracted lanthanides by diglycolamides

AA Peroutka, SS Galley, JC Shafer - Coordination Chemistry Reviews, 2023 - Elsevier
Many studies over the past few decades have been devoted to addressing the application of
diglycolamides (DGAs) for hydrometallurgical-based, f-element separations. Work to date …

Biological, biomolecular, and bio-inspired strategies for detection, extraction, and separations of lanthanides and actinides

JA Mattocks, JA Cotruvo - Chemical Society Reviews, 2020 - pubs.rsc.org
Lanthanides and actinides are elements of ever-increasing technological importance in the
modern world. However, the similar chemical and physical properties within these groups …

Structure activity relationship approach toward the improved separation of rare-earth elements using diglycolamides

D Stamberga, MR Healy, VS Bryantsev… - Inorganic …, 2020 - ACS Publications
The separation of adjacent lanthanides continues to be a challenge worldwide because of
the similar physical and chemical properties of these elements and a necessity to advance …

Coordination sphere of lanthanide aqua ions resolved with ab initio molecular dynamics and X-ray absorption spectroscopy

RC Shiery, JL Fulton, M Balasubramanian… - Inorganic …, 2021 - ACS Publications
To resolve the fleeting structures of lanthanide Ln3+ aqua ions in solution, we (i) performed
the first ab initio molecular dynamics (AIMD) simulations of the entire series of Ln3+ aqua …

Observation of a promethium complex in solution

DM Driscoll, FD White, S Pramanik, JD Einkauf… - Nature, 2024 - nature.com
Lanthanide rare-earth metals are ubiquitous in modern technologies,,,–, but we know little
about chemistry of the 61st element, promethium (Pm), a lanthanide that is highly radioactive …