Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

In this contribution, we provide an overview of the main avenues that have emerged in gold
coordination chemistry during the last years. The unique properties of gold have motivated …

For a while, the reactivity of gold complexes was largely dominated by their Lewis acid
behavior. In contrast to the other transition metals, the elementary steps of organometallic …

A combination of visible light photocatalysis and gold catalysis is applied to a ring expansion–
oxidative arylation reaction. The reaction provides an entry into functionalized cyclic ketones …

An efficient method for chemoselective cysteine arylation of unprotected peptides and
proteins using Au (III) organometallic complexes is reported. The bioconjugation reactions …

Environmental concerns have and will continue to have a significant role in determining how
chemistry is carried out. Chemists will be challenged to develop new, efficient synthetic …

Gold-catalyzed reactions have witnessed an exponential growth in the past decade. When
the unique modes of activation exhibited by gold species meet species with either …

Transition‐metal‐catalyzed cross‐coupling reactions are central to many organic synthesis
methodologies. Traditionally, Pd, Ni, Cu, and Fe catalysts are used to promote these …

Reductive elimination from partially or completely oxidized metal centers is a vital step in a
myriad of carbon–carbon and carbon–heteroatom bond‐forming reactions. One strategy for …

This Review showcases the ability of bi‐and tridentate ligands to stabilize gold in high
oxidation states through the formation of mono‐and biscyclometalated gold (III) complexes …