Electro-and solar-driven fuel synthesis with first row transition metal complexes

KE Dalle, J Warnan, JJ Leung, B Reuillard… - Chemical …, 2019 - ACS Publications
The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

[FeFe]-Hydrogenases: maturation and reactivity of enzymatic systems and overview of biomimetic models

JT Kleinhaus, F Wittkamp, S Yadav… - Chemical Society …, 2021 - pubs.rsc.org
While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

Biomimetic active sites on monolayered metal–organic frameworks for artificial photosynthesis

G Lan, Y Fan, W Shi, E You, SS Veroneau, W Lin - Nature Catalysis, 2022 - nature.com
Enzymes have evolved to catalyse challenging chemical transformations with high efficiency
and selectivity. Although a number of artificial systems have been developed to recapitulate …

[HTML][HTML] Artificial photosynthesis: molecular systems for catalytic water oxidation

MD Karkas, O Verho, EV Johnston… - Chemical reviews, 2014 - ACS Publications
The sustainable production of clean energy constitutes one of the most important scientific
challenges of the 21st century. Currently, the major part of the global energy supply is …

Biochemical and artificial pathways for the reduction of carbon dioxide, nitrite and the competing proton reduction: effect of 2 nd sphere interactions in catalysis

S Amanullah, P Saha, A Nayek, ME Ahmed… - Chemical Society …, 2021 - pubs.rsc.org
Reduction of oxides and oxoanions of carbon and nitrogen are of great contemporary
importance as they are crucial for a sustainable environment. Substantial research has been …

Powering the planet: Chemical challenges in solar energy utilization

NS Lewis, DG Nocera - Proceedings of the National …, 2006 - National Acad Sciences
Global energy consumption is projected to increase, even in the face of substantial declines
in energy intensity, at least 2-fold by midcentury relative to the present because of …

Hydrogen evolution catalyzed by cobaloximes

JL Dempsey, BS Brunschwig, JR Winkler… - Accounts of chemical …, 2009 - ACS Publications
Natural photosynthesis uses sunlight to drive the conversion of energy-poor molecules
(H2O, CO2) to energy-rich ones (O2,(CH2O) n). Scientists are working hard to develop …

Structural and functional analogues of the active sites of the [Fe]-,[NiFe]-, and [FeFe]-hydrogenases

C Tard, CJ Pickett - Chemical reviews, 2009 - ACS Publications
This article sets out to review the chemistry relating to the synthesis of structural and
functional analogues of the three classes of hydrogenases. This chemistry has grown …

Catalysts for Hydrogen Evolution from the [NiFe] Hydrogenase to the Ni2P(001) Surface:  The Importance of Ensemble Effect

P Liu, JA Rodriguez - Journal of the American Chemical Society, 2005 - ACS Publications
Density functional theory (DFT) was employed to investigate the behavior of a series of
catalysts used in the hydrogen evolution reaction (HER, 2H++ 2e-→ H2). The kinetics of the …

Hydrogen production by molecular photocatalysis

AJ Esswein, DG Nocera - Chemical reviews, 2007 - ACS Publications
A great technological challenge facing our global future is the development of a secure,
clean, and renewable energy source. 1-4 Rising standards of living in a growing world …