Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …

Abstract Der Begriff “frustrierte Lewis‐Paare”(FLPs) bezeichnet Kombinationen von Lewis‐
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …

The first example of a frustrated Lewis pair (FLP) solely constructed around transition metal
centers is described in this work. We have focused on the established capacity of Au (I) and …

Frustrated Lewis pair chemistry has taken a steep development in the recent years. It offers
possibilities of developing new variants of known reactions and of finding new chemical …

A joint experimental/computational effort to elucidate the mechanism of dihydrogen
activation by a gold (I)/platinum (0) metal‐only frustrated Lewis pair (FLP) is described …

Direct Mannich‐type reactions that afford both α‐and β‐amino esters by the reaction of a
broad range of carbonyl compounds and aldimines are disclosed. The transformation is …

Methyl anion abstraction from Cp* 2Zr (CH3) OCH2CH2N i Pr2 (13) with trityl cation
generates [Cp* 2Zr (OCH2CH2N i Pr2)]+(14). Complex 14 behaves as a reactive Zr+/amine …

Abstract Oxophosphonium ions (R2P= O)+ are fascinating chemical intermediates related to
the well‐known acylium cations (RC= O)+, and comprise a tricoordinate phosphorus (V) …

Half‐sandwich manganese methylenephosphonium complexes [Cp (CO) 2Mn (η2‐R2P C
(H) Ph)] BF4 were obtained in high yield through a straightforward reaction sequence …

The η2-formyl borane system 3 is readily available by carbonylation of the vicinal P/BH
frustrated Lewis pair (FLP) 1. It serves as a frustrated C/B Lewis pair toward carbon dioxide …