Five new ternary indium-arsenides discovered. Synthesis and structural characterization of the Zintl phases Sr3In2As4, Ba3In2As4, Eu3In2As4, Sr5In2As6 and …

AB Childs, S Baranets, S Bobev - Journal of Solid State Chemistry, 2019 - Elsevier
Five new ternary indium aresenides, AE 3 In 2 As 4 (AE= Sr, Ba, Eu), and AE 5 In 2 As 6
(AE= Sr, Eu), have been synthesized using molten metal In, Pb, and Sn fluxes. Structure …

Eu11Zn4Sn2As12: A Ferromagnetic Zintl Semiconductor with a Layered Structure Featuring Extended Zn4As6 Sheets and Ethane-like Sn2As6 Units

KP Devlin, N Kazem, JV Zaikina, JA Cooley… - Chemistry of …, 2018 - ACS Publications
We report the synthesis, structure, and magnetic properties of a new Zintl phase and
structure type, Eu11Zn4Sn2As12. The structure and composition of this phase have been …

First principles calculations of the properties of Sr3In2As4 and Eu3In2As4 Zintl phases

MN Rasul, M Mehmood, T Hu, A Hussain… - Journal of Materials …, 2023 - Springer
Structural, bonding, electronic, elastic and optical properties of X3In2As4 (X= Sr, Eu) Zintl
phases are calculated theoretically. We used ab-initio simulations using the Vienna Ab Initio …

Thermoelectric Properties of Ba1.9Ca2.4Mg9.7Si7: A New Silicide Zintl Phase with the Zr2Fe12P7 Structure Type

K Silsby, F Sui, X Ma, SM Kauzlarich… - Chemistry of …, 2015 - ACS Publications
Ba1. 9Ca2. 4Mg9. 7Si7 was grown as large crystals from the reaction of silicon with barium
and calcium in Mg/Al flux. This compound is a charge-balanced Zintl phase with the …

Complex physical properties of EuMgSi–a complementary study by neutron powder diffraction and 151 Eu Mössbauer spectroscopy

O Niehaus, DH Ryan, R Flacau, P Lemoine… - Journal of Materials …, 2015 - pubs.rsc.org
X-ray pure samples of EuMgSi were synthesized by reactions of the elements in sealed
niobium tubes using a high frequency and subsequently a resistance furnace. The structure …

Investigation of the Precipitation Behavior in Aluminum Based Alloys

MS Khushaim - 2015 - repository.kaust.edu.sa
The transportation industries are constantly striving to achieve minimum weight to cut fuel
consumption and improve overall performance. Different innovative design strategies have …

Evidence of a Mixed Magnetic Phase in EuMgGe: A Semimetallic Zintl Compound with TiNiSi Structure Type

A Slabon, E Cuervo‐Reyes, O Niehaus… - Zeitschrift für …, 2014 - Wiley Online Library
Abstract The ternary Zintl phase EuMgGe was synthesized from the elements, and its
structure solved by single‐crystal X‐ray diffraction. Chemical bonding is discussed, by …

Metal flux growth of complex alkaline earth/rare earth metal silicides with a homologous series of metal phosphide structure types

G Vasquez, SE Latturner - Chemistry of Materials, 2018 - ACS Publications
Three new metal silicides were grown as competing products from reactions of silicon with
barium and ytterbium in Mg/Al flux; the dominant product is determined by the heating profile …

Crystal and Electronic Structures and Magnetic Properties of Eu3Tt2As4 (Tt = Si, Ge)

XC Liu, SQ Xia, XW Lei, MY Pan… - European Journal of …, 2014 - Wiley Online Library
Two new europium‐containing Zintl phases, Eu3Si2As4 and Eu3Ge2As4, were discovered
from metal flux reactions and their structures were identified by using single‐crystal X‐ray …

RFe2MgxAl8− x (R= La–Nd and Sm; x≈ 0.8): Flux synthesis, structure, magnetic and electrical properties

X Ma, P Chai, B Chen, E Lochner… - Journal of Solid State …, 2015 - Elsevier
Single crystals of Mg-substituted CeFe 2 Al 8 type intermetallics RFe 2 Mg x Al 8–x (R= La–
Nd and Sm; x≤ 1) were grown by reacting iron and rare earth metals in 1: 1 Mg/Al mixed …