Corannulene: A curved polyarene building block for the construction of functional materials

MC Stuparu - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus This Account describes a body of research in the design and synthesis of
molecular materials prepared from corannulene. Corannulene (C20H10) is a molecular …

Synthesis of corannulene-based nanographenes

EM Muzammil, D Halilovic, MC Stuparu - Communications Chemistry, 2019 - nature.com
Abstract Corannulene (C20H10) is a polycyclic hydrocarbon in which five six-membered
rings surround a central five-membered ring to construct a bowl-like aromatic structure. Here …

Ring-fused 1, 4-dihydro [1, 2, 4] triazin-4-yls through photocyclization

P Bartos, VG Young Jr, P Kaszynski - Organic Letters, 2020 - ACS Publications
Halogen lamp irradiation of benzo [e][1, 2, 4] triazines 2 [X] in CH2Cl2 solutions leads to
planar ring-fused 1, 4-dihydro [1, 2, 4] triazin-4-yl radicals 1 through a novel, potentially …

Bioconjugation strategies for tobacco mild green mosaic virus

I González‐Gamboa, AA Caparco… - …, 2022 - Wiley Online Library
Tobacco mild green mosaic virus (TMGMV) is a plant virus closely related to Tobacco
mosaic virus (TMV), sharing many of its structural and chemical features. These rod‐shaped …

Photochemical synthesis and electronic properties of extended corannulenes with variable fluorination pattern

D Halilovic, M Budanović, ZR Wong… - The Journal of …, 2018 - ACS Publications
The first family of extended and fluorinated corannulenes is prepared through a highly
efficient and modular synthetic strategy. In this strategy, corannulene aldehyde could be …

Synthesis of Phenacene–Helicene Hybrids by Directed Remote Metalation

S Kancherla, KB Jørgensen - The Journal of organic chemistry, 2020 - ACS Publications
Polycyclic aromatic hydrocarbons (PAHs) with six and seven rings were synthesized via
directed metalation and cross-coupling of chrysenyl N, N-diethyl carboxamides with o-tolyl …

Molecular simulation of folding and aggregation of multi-core polycyclic aromatic compounds

X Sun, H Zeng, T Tang - Journal of Molecular Liquids, 2020 - Elsevier
Compared with polycyclic aromatic compounds (PACs) that have a single polyaromatic core,
those having multiple cores connected by aliphatic chains can undergo significant internal …

Anaerobic photocyclization of ortho‐dialkylamino substituted stiff‐stilbenes

YN Hung, YC Wang, ZJ Chen… - Journal of the Chinese …, 2024 - Wiley Online Library
The photocyclization of diarylethenes toward polycyclic aromatic hydrocarbons and analogs
has been well‐documented. However, stiff‐stilbene was reported to be inactive, and …

“Upper” Ring Expansion of the Planar Blatter Radical via Photocyclization: Limitations and Impact on the Electronic Structure

GA Zissimou, P Bartos, A Pietrzak… - The Journal of Organic …, 2022 - ACS Publications
Photocyclization of 8-aryloxybenzo [e][1, 2, 4] triazines leads to the formation of π-expanded
flat Blatter radicals for three phenanthryloxy and pyren-1-yloxy derivatives, whereas no …

Bilateral Aromatic Extension of Corannulene Nucleus

D Halilovic, D Csókás, RD Webster… - European Journal of …, 2022 - Wiley Online Library
Herein we show that a dibromo imide derivative of corannulene could be subjected to a
palladium‐catalyzed Heck reaction in order to install aryl vinylene groups in a bilateral …