An evolving view on biogeochemical cycling of iron

A Kappler, C Bryce, M Mansor, U Lueder… - Nature Reviews …, 2021 - nature.com
Biogeochemical cycling of iron is crucial to many environmental processes, such as ocean
productivity, carbon storage, greenhouse gas emissions and the fate of nutrients, toxic …

Fe (II) redox chemistry in the environment

J Huang, A Jones, TD Waite, Y Chen, X Huang… - Chemical …, 2021 - ACS Publications
Iron (Fe) is the fourth most abundant element in the earth's crust and plays important roles in
both biological and chemical processes. The redox reactivity of various Fe (II) forms has …

Oxide–and silicate–water interfaces and their roles in technology and the environment

JL Bañuelos, E Borguet, GE Brown Jr… - Chemical …, 2023 - ACS Publications
Interfacial reactions drive all elemental cycling on Earth and play pivotal roles in human
activities such as agriculture, water purification, energy production and storage …

Fenton reaction-controversy concerning the chemistry

K Barbusiński - Ecological Chemistry and Engineering. S, 2009 - infona.pl
There is something intriguing and at the same time fascinating that a simple reaction (of
Fe2+ ions), which was observed by HJH Fenton over 110 years ago, proves to be very …

Synthesis of iron-based metal-organic framework MIL-53 as an efficient catalyst to activate persulfate for the degradation of Orange G in aqueous solution

M Pu, Z Guan, Y Ma, J Wan, Y Wang… - Applied Catalysis A …, 2018 - Elsevier
A series of MIL-53 (Fe) materials was synthesized using a solvothermal method under
different temperature and time conditions and were used as catalysts to activate persulfate …

Disassembling iron availability to phytoplankton

Y Shaked, H Lis - Frontiers in Microbiology, 2012 - frontiersin.org
The bioavailability of iron to microorganisms and its underlying mechanisms have far
reaching repercussions to many natural systems and diverse fields of research, including …

Potentiation of hydrogen peroxide toxicity: From catalase inhibition to stable DNA-iron complexes

T Mahaseth, A Kuzminov - Mutation Research/Reviews in Mutation …, 2017 - Elsevier
Abstract Hydrogen peroxide (H 2 O 2) is unique among general toxins, because it is stable
in abiotic environments at ambient temperature and neutral pH, yet rapidly kills any type of …

Influence of organic ligands on the redox properties of Fe (II) as determined by mediated electrochemical oxidation

JM Hudson, GW Luther III, YP Chin - Environmental Science & …, 2022 - ACS Publications
Fe (II) has been extensively studied due to its importance as a reductant in biogeochemical
processes and contaminant attenuation. Previous studies have shown that ligands can alter …

Photochemistry of iron in aquatic environments

U Lueder, BB Jørgensen, A Kappler… - … Science: Processes & …, 2020 - pubs.rsc.org
Light energy is a driver for many biogeochemical element cycles in aquatic systems. The
sunlight-induced photochemical reduction of ferric iron (Fe (III) photoreduction) to ferrous …

The role of one-and two-electron transfer reactions in forming thermodynamically unstable intermediates as barriers in multi-electron redox reactions

GW Luther - Aquatic Geochemistry, 2010 - Springer
In the aquatic geochemical literature, a redox half-reaction is normally written for a multi-
electron process (n> 2); eg, sulfide oxidation to sulfate. When coupling two multi-electron …