Chemoselective C (sp2)–C (sp2) doubly decarbonylative cross-electrophile coupling enabled by palladium catalysis: Reaction development and mechanism studies
Z Song, N Zhang, W Jiao, C He, X Huang, G Luo… - Journal of Catalysis, 2024 - Elsevier
Transition metal-catalyzed cross-electrophile coupling of two electrophiles has proved to be
a powerful and step-economic strategy for the construction of C–C bonds in organic …
a powerful and step-economic strategy for the construction of C–C bonds in organic …
Light-Driven Photocatalyst-Free Synthesis of β, δ-Functionalized Ketones from Aldehydes
Q Mou, T Han, M Tian, M Liu - The Journal of Organic Chemistry, 2024 - ACS Publications
The synthesis of ketones has been a long focus of chemistry research, on account of its
unique reactivity. Herein, we report a simple light-driven photocatalyst-free synthesis of β, δ …
unique reactivity. Herein, we report a simple light-driven photocatalyst-free synthesis of β, δ …
Decarbonylative C (sp 2)–C (sp 2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium/cobalt co-catalysis
C He, Z Song, W Yao, R Lin, Y Ma - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
Transition metal-catalyzed reductive cross-coupling has emerged as a powerful tool for
forging C–C bonds. Despite significant advances, decarbonylative reductive coupling of …
forging C–C bonds. Despite significant advances, decarbonylative reductive coupling of …
A new and the first metal organic framework for the synthesis of aryl ketones via carbonyl‐Heck cross‐coupling reaction of aryl halides and aldehydes
S Sobhani, M Rouzifar, A Farrokhi… - Applied …, 2024 - Wiley Online Library
A new MOF (Co‐TIST) was synthesized from 2, 4, 6‐tris (imidazol‐1‐yl)‐1, 3, 5‐s‐triazine
(TIST) and cobalt nitrate. TIST was prepared from the reaction of cyanuric chloride and …
(TIST) and cobalt nitrate. TIST was prepared from the reaction of cyanuric chloride and …
Olefination of aldehydes with alpha-halo redox-active esters
Z Liu, WH Liu - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
Olefin synthesis is a fundamentally important process in organic chemistry. Among the
numerous approaches to obtaining olefins such as alcohol/halide eliminations, alkyne …
numerous approaches to obtaining olefins such as alcohol/halide eliminations, alkyne …
Fe-catalyzed B–H and Si–H insertion reactions of gem-dihaloalkanes
X Wang, Z Wang - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
Transition metal-catalyzed B–H and Si–H insertion reactions afford efficient routes to the
synthesis of valuable organoboranes and organosilicon compounds. Typically, these …
synthesis of valuable organoboranes and organosilicon compounds. Typically, these …
Rapid and Practical Synthesis of gem‐Dibromoalkanes from Aldehydes by Tribromide Reagent
B Ren, J Xu, C Liu - Chemistry–An Asian Journal, 2024 - Wiley Online Library
Abstract gem‐Dibromoalkanes are important synthetic building block in organic chemistry,
but their preparation is still troublesome. Herein, we have developed a simple and practical …
but their preparation is still troublesome. Herein, we have developed a simple and practical …
Selective Transformations Mediated by Group 4 Metal Cyclopentadienyl Complexes
This chapter provides a brief overview of chemical transformations or syntheses mediated or
catalysed by complexes of group 4 elements containing cyclopentadienyl and related …
catalysed by complexes of group 4 elements containing cyclopentadienyl and related …
From Carboxylic Acid Derivatives to Ketones: Modular Ketone Synthesis via Catalytic Olefination
D Trauner, Y Li - Synfacts, 2023 - thieme-connect.com
A protocol for synthesizing ketones from carboxylic acid derivatives via olefination and
electrophilic transformation using low-valent Ti catalysis is presented. Due to mild conditions …
electrophilic transformation using low-valent Ti catalysis is presented. Due to mild conditions …