Protons and hydroxide ions in aqueous systems

N Agmon, HJ Bakker, RK Campen… - Chemical …, 2016 - ACS Publications
Understanding the structure and dynamics of water's constituent ions, proton and hydroxide,
has been a subject of numerous experimental and theoretical studies over the last century …

Multiscale modeling of aqueous electric double layers

M Becker, P Loche, M Rezaei, A Wolde-Kidan… - Chemical …, 2023 - ACS Publications
From the stability of colloidal suspensions to the charging of electrodes, electric double
layers play a pivotal role in aqueous systems. The interactions between interfaces, water …

Second harmonic and sum-frequency generation from aqueous interfaces is modulated by interference

G Gonella, C Lütgebaucks… - The Journal of …, 2016 - ACS Publications
The interfacial region of aqueous systems also known as the electrical double layer can be
characterized on the molecular level with second harmonic and sum-frequency generation …

The Solvation-Induced Onsager Reaction Field Rather than the Double-Layer Field Controls CO2 Reduction on Gold

Q Zhu, SK Wallentine, GH Deng, JA Rebstock… - JACS Au, 2022 - ACS Publications
The selectivity and activity of the carbon dioxide reduction (CO2R) reaction are sensitive
functions of the electrolyte cation. By measuring the vibrational Stark shift of in situ …

Ordered water layer on the macroscopically hydrophobic fluorinated polymer surface and its ultrafast vibrational dynamics

J Zhang, J Tan, R Pei, S Ye, Y Luo - Journal of the American …, 2021 - ACS Publications
Hydrophobic-like water monolayers have been predicted at the metal and some polar
surfaces by theoretical simulations. However, direct experimental evidence for the presence …

Toward ab initio molecular dynamics modeling for sum-frequency generation spectra; an efficient algorithm based on surface-specific velocity-velocity correlation …

T Ohto, K Usui, T Hasegawa, M Bonn… - The Journal of Chemical …, 2015 - pubs.aip.org
Interfacial water structures have been studied intensively by probing the O–H stretch mode
of water molecules using sum-frequency generation (SFG) spectroscopy. This surface …

Progress in phase-sensitive sum frequency generation spectroscopy

S Yamaguchi, T Otosu - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
Sum frequency generation (SFG) spectroscopy is a unique and powerful tool for
investigating surfaces and interfaces at the molecular level. Phase-sensitive SFG (PS-SFG) …

[HTML][HTML] A water droplet-powered sensor based on charge transfer to a flow-through front surface electrode

LE Helseth - Nano Energy, 2020 - Elsevier
A water droplet sensor based on a flow-through front surface electrode is demonstrated. It is
shown that a triboelectric nanogenerator based on a metal-dielectric junction can be utilized …

Why are water droplets highly mobile on nanostructured oil-impregnated surfaces?

C Zhang, S Adera, J Aizenberg… - ACS Applied Materials & …, 2021 - ACS Publications
Porous lubricated surfaces (aka slippery liquid-infused porous surfaces, SLIPS) have been
demonstrated to repel various liquids. The origin of this repellency, however, is not fully …

Water-induced restructuring of the surface of a deep eutectic solvent

R Gera, CJ Moll, A Bhattacherjee… - The journal of physical …, 2022 - ACS Publications
We study the molecular-scale structure of the surface of Reline, a DES made from urea and
choline chloride, using heterodyne-detected vibrational sum frequency generation (HD …