[HTML][HTML] Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds

A Tilgner, T Schaefer, B Alexander… - Atmospheric …, 2021 - acp.copernicus.org
The acidity of aqueous atmospheric solutions is a key parameter driving both the partitioning
of semi-volatile acidic and basic trace gases and their aqueous-phase chemistry. In addition …

Aqueous photochemistry of 2-oxocarboxylic acids: evidence, mechanisms, and atmospheric impact

MI Guzman, AJ Eugene - Molecules, 2021 - mdpi.com
Atmospheric organic aerosols play a major role in climate, demanding a better
understanding of their formation mechanisms by contributing multiphase chemical reactions …

Water–air interfaces as environments to address the water paradox in prebiotic chemistry: a physical chemistry perspective

AM Deal, RJ Rapf, V Vaida - The Journal of Physical Chemistry A, 2021 - ACS Publications
The asymmetric water–air interface provides a dynamic aqueous environment with
properties that are often very different than bulk aqueous or gaseous phases and promotes …

Mass spectrometry analysis in atmospheric chemistry

J Laskin, A Laskin, SA Nizkorodov - Analytical chemistry, 2018 - elibrary.ru
Mass Spectrometry Analysis in Atmospheric Chemistry КОРЗИНА ПОИСК НАВИГАТОР
ЖУРНАЛЫ КНИГИ ПАТЕНТЫ ПОИСК АВТОРЫ ОРГАНИЗАЦИИ КЛЮЧЕВЫЕ СЛОВА …

Photoinduced oxidation reactions at the air–water interface

JM Anglada, MTC Martins-Costa… - Journal of the …, 2020 - ACS Publications
Chemistry on water is a fascinating area of research. The surface of water and the interfaces
between water and air or hydrophobic media represent asymmetric environments with …

Chemistry and photochemistry of pyruvic acid at the air–water interface

KJ Kappes, AM Deal, MF Jespersen… - The Journal of …, 2021 - ACS Publications
Interfacial regions are unique chemical reaction environments that can promote chemistry
not found elsewhere. The air–water interface is ubiquitous in the natural environment in the …

Size-Dependent Sigmoidal Reaction Kinetics for Pyruvic Acid Condensation at the Air–Water Interface in Aqueous Microdroplets

M Li, C Boothby, RE Continetti… - Journal of the American …, 2023 - ACS Publications
The chemistry of pyruvic acid (PA) under thermal dark conditions is limited in bulk solutions,
but in microdroplets it is shown to readily occur. Utilizing in situ micro-Raman spectroscopy …

pH dependence of the aqueous photochemistry of α-keto acids

RJ Rapf, MR Dooley, K Kappes… - The Journal of …, 2017 - ACS Publications
α-Keto acids are important, atmospherically relevant species, and their photochemistry has
been considered in the formation and processing of aerosols. Despite their atmospheric …

Reactivity of ketyl and acetyl radicals from direct solar actinic photolysis of aqueous pyruvic acid

AJ Eugene, MI Guzman - The Journal of Physical Chemistry A, 2017 - ACS Publications
The variable composition of secondary organic aerosols (SOA) contributes to the large
uncertainty for predicting radiative forcing. A better understanding of the reaction …

A cyanosulfidic origin of the Krebs cycle

DJ Ritson - Science Advances, 2021 - science.org
The centrality of the Krebs cycle in metabolism has long been interpreted as evidence of its
antiquity, and consequently, questions regarding its provenance, and whether it initially …