Conjugated poly-ynes and poly (metalla-ynes) constitute an important class of new materials
with potential application in various domains of science. The key factors responsible for the …

In mixed-valence (MV) systems essentially identical, more or less electronically coupled,
redox centres are brought into formally different oxidation states by removal or addition of an …

Reaction of the butadiynyl complex (η5-C5Me5) Re (NO)(PPh3)(C⋮ CC⋮ CH)(ReC 4 H)
with Cu (OAc) 2 (pyridine, 80° C) gives the μ-octatetraynediyl complex ReC 8 Re (70%) …

Reviewed herein are key aspects of the recent progress in the chemistry of σ-alkynyl
compounds of Ru2 (LL) 4, where LL is an N, N '-bidentate bridging ligand. Synthetic …

While small carbon molecules have been found in locations as diverse as interstellar
molecular clouds, carbon stars, hydrocarbon flames and laserablated carbon, bulk …

In this review, the electronic and structural properties of different organometallic wires
containing the (dppe) Cp* Fe organometallic electrophore are thoroughly discussed. Results …

In this Perspective, we highlight the non-innocent behaviour of the bridging ligand in
organometallic polynuclear metallic complexes displaying metal-carbon σ bonds between …

The complexes {Cp*(PP) Ru} 2 (μ-C⋮ CC⋮ C)(PP= dppm 5a, dppe 5b) have been
synthesized from RuCl (PP) Cp*(1a/b) via the corresponding vinylidenes [Ru (C CH2)(PP) …

Polyyn-diyls capped by Ru2 (ap) 4 termini (ap= 2-anilinopyridinate), that is,[Ru2 (ap) 4](μ-C,
C '-C2 m)[Ru2 (ap) 4](compounds 1− 5 with m= 1− 4 and 6), were synthesized through either …

Reported herein is a series of Ru2 (Xap) 4 capped polyyn-diyl compounds, where Xap is
either 2-anilinopyridinate (ap) or its aniline substituted derivatives. Symmetric [Ru2 (Xap) …