First-row transition metal (de) hydrogenation catalysis based on functional pincer ligands

L Alig, M Fritz, S Schneider - Chemical reviews, 2018 - ACS Publications
The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …

Spatiotemporal control for integrated catalysis

S Deng, BJ Jolly, JR Wilkes, Y Mu, JA Byers… - Nature Reviews …, 2023 - nature.com
Integrated catalysis is an emerging methodology that can streamline the multi-step synthesis
of complicated products in a single reaction vessel, achieving a high degree of control and …

Redox-controlled polymerization and copolymerization

C Chen - ACS Catalysis, 2018 - ACS Publications
Redox control is an attractive strategy for modulating polymerization processes as well as
the compositions, microstructures, and properties of polymer products. This perspective …

Recent advances in externally controlled ring-opening polymerisations

S Kaler, MD Jones - Dalton Transactions, 2022 - pubs.rsc.org
Switchable catalysis is a powerful tool in the polymer chemist's toolbox as it allows on
demand access to a variety of polymer architectures. Switchable catalysts operate by the …

Coordination ring-opening polymerization of cyclic esters: A critical overview of DFT modeling and visualization of the reaction mechanisms

I Nifant'ev, P Ivchenko - Molecules, 2019 - mdpi.com
Ring-opening polymerization (ROP) of cyclic esters (lactones, lactides, cyclic carbonates
and phosphates) is an effective tool to synthesize biocompatible and biodegradable …

[图书][B] Computational Methods in Organometallic Catalysis: From Elementary Reactions to Mechanisms

Y Lan - 2021 - books.google.com
Computational Methods in Organometallic Catalysis Discover recent advances in the
mechanistic study of organometallic catalysis In Computational Methods in Organometallic …

Reversible On/Off Switching of Lactide Cyclopolymerization with a Redox-Active Formazanate Ligand

F de Vries, E Otten - ACS catalysis, 2022 - ACS Publications
Redox-switching of a formazanate zinc catalyst in ring-opening polymerization (ROP) of
lactide is described. Using a redox-active ligand bound to an inert metal ion (Zn2+) allows …

Discrete iron-based complexes: Applications in homogeneous coordination-insertion polymerization catalysis

Y Champouret, OH Hashmi, M Visseaux - Coordination Chemistry Reviews, 2019 - Elsevier
Catalysis based on well-defined iron complexes has experienced a very strong growth over
the last decade, driven by the need to develop a chemistry that is increasingly in line with …

Electrochemically switchable polymerization from surface-anchored molecular catalysts

M Qi, H Zhang, Q Dong, J Li, RA Musgrave, Y Zhao… - Chemical …, 2021 - pubs.rsc.org
Redox-switchable polymerizations of lactide and epoxides were extended to the solid state
by anchoring an iron-based polymerization catalyst to TiO2 nanoparticles. The reactivity of …

Adding Polypeptides to the Toolbox for Redox-Switchable Polymerization and Copolymerization Catalysis

MS Thompson, SA Johnson, SA Gonsales… - …, 2023 - ACS Publications
Bis (imino) pyridine (BIP) iron alkoxide complexes act as catalysts to efficiently polymerize N-
carboxyanhydrides (NCAs), including γ-benzyl-l-glutamate NCA (BLG-NCA) and sarcosine …