S Deng, BJ Jolly, JR Wilkes, Y Mu, JA Byers… - Nature Reviews …, 2023 - nature.com
Integrated catalysis is an emerging methodology that can streamline the multi-step synthesis of complicated products in a single reaction vessel, achieving a high degree of control and …
Redox control is an attractive strategy for modulating polymerization processes as well as the compositions, microstructures, and properties of polymer products. This perspective …
S Kaler, MD Jones - Dalton Transactions, 2022 - pubs.rsc.org
Switchable catalysis is a powerful tool in the polymer chemist's toolbox as it allows on demand access to a variety of polymer architectures. Switchable catalysts operate by the …
I Nifant'ev, P Ivchenko - Molecules, 2019 - mdpi.com
Ring-opening polymerization (ROP) of cyclic esters (lactones, lactides, cyclic carbonates and phosphates) is an effective tool to synthesize biocompatible and biodegradable …
Computational Methods in Organometallic Catalysis Discover recent advances in the mechanistic study of organometallic catalysis In Computational Methods in Organometallic …
F de Vries, E Otten - ACS catalysis, 2022 - ACS Publications
Redox-switching of a formazanate zinc catalyst in ring-opening polymerization (ROP) of lactide is described. Using a redox-active ligand bound to an inert metal ion (Zn2+) allows …
Catalysis based on well-defined iron complexes has experienced a very strong growth over the last decade, driven by the need to develop a chemistry that is increasingly in line with …
Redox-switchable polymerizations of lactide and epoxides were extended to the solid state by anchoring an iron-based polymerization catalyst to TiO2 nanoparticles. The reactivity of …
MS Thompson, SA Johnson, SA Gonsales… - …, 2023 - ACS Publications
Bis (imino) pyridine (BIP) iron alkoxide complexes act as catalysts to efficiently polymerize N- carboxyanhydrides (NCAs), including γ-benzyl-l-glutamate NCA (BLG-NCA) and sarcosine …