This review deals with some key synthetic developments based on the use of iron or cobalt
complexes to promote radical reactivity which have been devised over the last decades. We …

Catalysis based on precious metals has reached an incredible level of sophistication and
has found widespread use and application, both in academia and in industry. However …

Single-electron oxidation and α-deprotonation of tertiary anilines using Fe (phen) 3 (PF6) 3
afford α-aminoalkyl radicals, which can be coupled with electrophilic partners to afford …

Electrocatalysis enables the construction of C–C bonds under mild conditions via controlled
formation of carbon-centered radicals. For sequences initiated by alkyl halide reduction …

Computational Methods in Organometallic Catalysis Discover recent advances in the
mechanistic study of organometallic catalysis In Computational Methods in Organometallic …

Enamines are electron-rich compounds bearing intriguing redox properties. Herein, a series
of secondary enamines condensed from primary amine and β-ketocarbonyls were …

The iron (III)–polypyridyl complex and its derivatives showed sufficient oxidizing potential to
act as a one-electron oxidant, producing radical cations from olefins and promoting the …

The development of photocascades that rapidly transform simple and readily accessible
furan substrates into polycyclic alkaloid frameworks or erythrina natural products is …

Radical cyclizations are most often achieved with Bu3SnH in the presence of a radical
initiator, but environmental considerations demand that alternative reagents be developed …

diazaphospholenes hydrides (DAP‐Hs) are highly nucleophilic organic hydrides serving as
main‐group catalysts for a range of attractive transformations. DAP hydrides can act as …