Hierarchical Study of the Reactions of Hydrogen Atoms with Alkenes: A Theoretical Study of the Reactions of Hydrogen Atoms with C2–C4 Alkenes

J Power, KP Somers, SS Nagaraja… - The Journal of Physical …, 2021 - ACS Publications
The present study complements our previous studies of the reactions of hydrogen atoms
with C5 alkene species including 1-and 2-pentene and the branched isomers (2-methyl-1 …

The atmospheric oxidation of CH 3 OOH by the OH radical: the effect of water vapor

JM Anglada, R Crehuet, M Martins-Costa… - Physical Chemistry …, 2017 - pubs.rsc.org
The atmospheric oxidation of methyl hydroperoxide by the hydroxyl radical has been
investigated employing high level theoretical methods. This reaction is important in the …

Photodissociation dynamics of the ortho-and para-xylyl radicals

K Pachner, M Steglich, P Hemberger… - The Journal of chemical …, 2017 - pubs.aip.org
The photodissociation dynamics of the C 8 H 9 isomers ortho-and para-xylyl are investigated
in a free jet. The xylyl radicals are generated by flash pyrolysis from 2-(2-methylphenyl)-and …

Isomer Identification in Flames with Double-Imaging Photoelectron/Photoion Coincidence Spectroscopy (i2PEPICO) using Measured and Calculated Reference …

J Pieper, S Schmitt, C Hemken, E Davies… - Zeitschrift für …, 2018 - degruyter.com
Double-imaging photoelectron/photoion coincidence (i2PEPICO) spectroscopy using a
multiplexing, time-efficient, fixed-photon-energy approach offers important opportunities of …

Photodissociation of Benzoyl Chloride: A Velocity Map Imaging Study Using VUV Detection of Chlorine Atoms

CT Matthaei, DP Mukhopadhyay… - The Journal of Physical …, 2021 - ACS Publications
UV photodissociation of benzoyl chloride, Ph–CO–Cl, is associated with the loss of a
chlorine atom. Here we excite benzoyl chloride to the S1, S2, and S3 excited states at 237 …

Roaming dissociation of ethyl radicals

A Matsugi - The journal of physical chemistry letters, 2013 - ACS Publications
Previous studies on the photodissociation of C2H5 reported rate constants for H-atom
formation several orders of magnitude smaller than that predicted by Rice–Ramsperger …

Insights into plasma‐assisted polymerization at atmospheric pressure by spectroscopic diagnostics

F Barletta, C Leys, V Colombo… - Plasma Processes …, 2020 - Wiley Online Library
In the present work, a polydiagnostic study of an atmospheric pressure plasma jet
specifically designed for the deposition of coatings by using an Ar/tetraethyl orthosilicate …

Photoinduced C–H bond fission in prototypical organic molecules and radicals

MNR Ashfold, RA Ingle, TNV Karsili… - Physical Chemistry …, 2019 - pubs.rsc.org
Recent experimental and computational advances have heralded huge progress in the
range and the detail of the database pertaining to photoinduced C–H bond fission …

The 3s versus 3p Rydberg state photodissociation dynamics of the ethyl radical

SM Poullain, DV Chicharro, A Zanchet… - Physical Chemistry …, 2019 - pubs.rsc.org
The photodissociation dynamics of the ethyl radical following excitation into the 3s and 3p
Rydberg states are revisited in a joint experimental and theoretical study. Two different …

Site-specific hydrogen-atom elimination in photoexcited ethyl radical

DV Chicharro, SM Poullain, A Zanchet… - Chemical …, 2019 - pubs.rsc.org
The photochemistry of the ethyl radical following excitation to the 3p Rydberg state is
investigated in a joint experimental and theoretical study. Velocity map images for hydrogen …