The quest to find milder and more sustainable methods to generate highly reactive, carbon-
centred intermediates has led to a resurgence of interest in radical chemistry. In particular …

The exceptional versatility of carboxylic acids has been extensively exploited in organic
synthesis across several decades. There has been a recent upsurge of radical …

Covalent organic frameworks (COFs) are structurally tuneable, porous and crystalline
polymers constructed through the covalent attachment of small organic building blocks as …

Visible light‐mediated direct decarboxylation of carboxylic acids with an acridine
photocatalyst is a convenient and powerful method to generate carbon‐centered radicals in …

sulfinamides, sulfonamides, and sulfonimidamides are in-demand motifs in medicinal
chemistry, yet methods for the synthesis of alkyl variants that start from simple, readily …

We report a photoinduced iron/copper dual-catalytic strategy for the radical decarboxylation
functionalization of aliphatic carboxylic acids. The photoinduced ligand-to-iron charge …

The reactivity of the sulfonyl group varies dramatically from nucleophilic sulfinates through
chemically robust sulfones to electrophilic sulfonyl halides—a feature that has been used …

Sulfinamides are some of the most centrally important four-valent sulfur compounds that
serve as critical entry points to an array of emergent medicinal functional groups, molecular …

We report herein a protocol for the selective activation of C (sp 3)–H bonds based on the
interplay of two readily available organic catalysts and their successful implementation in …

The intermediate oxidation state of sulfoxides is central to the plethora of their applications in
chemistry and medicine, yet it presents challenges for an efficient synthetic access, limiting …