Some highlights from the development and use of bulky monodentate ligands

PP Power - Journal of organometallic chemistry, 2004 - Elsevier
The development of bulky monodentate alkoxide, chalcogenolate (ER, E= S, Se or Te),
amide, pnictide (ER2= N, P, As), alkyl, aryl and silyl ligands is briefly surveyed. These …

Three-coordinate cationic aluminum alkyl complexes incorporating β-diketiminate ligands

CE Radzewich, IA Guzei, RF Jordan - Journal of the American …, 1999 - ACS Publications
Low-coordinate cationic aluminum complexes are expected to be highly electrophilic and
therefore are of interest for Lewis acid catalysis, olefin polymerization, and other potential …

Recent advances in the chemistry of the Group 13 metals: hydride derivatives and compounds involving multiply bonded Group 13 metal atoms

AJ Downs - Coordination chemistry reviews, 1999 - Elsevier
Two aspects of Group 13 metal chemistry are surveyed in the light of recent research,
particularly that reported in the period 1992–1998. The first concerns compounds containing …

Sterically encumbered iron (II) thiolate complexes: synthesis and structure of trigonal planar [Fe (SR) 3]-(R= 2, 4, 6-t-Bu3C6H2) and Mössbauer spectra of two-and …

FM MacDonnell, K Ruhlandt-Senge, JJ Ellison… - Inorganic …, 1995 - ACS Publications
Complex 5 expands the family of homoleptic molecular Fe (II) thiolates to five structural
types; complexes 5 and 6 with two previously reported species of the type [Fe2 (SR) 4] …

U(SMes*)n, (n = 3, 4) and Ln(SMes*)3 (Ln = La, Ce, Pr, Nd):  Lanthanide(III)/Actinide(III) Differentiation in Agostic Interactions and an Unprecedented η3 Ligation …

M Roger, N Barros, T Arliguie, P Thuéry… - Journal of the …, 2006 - ACS Publications
Reaction of U (NEt2) 4 with HS-2, 4, 6-tBu3C6H2 (HSMes*) gave U (SMes*) 3 (NEt2)(py)(1),
whereas similar treatment of U [N (SiMe3) SiMe2CH2][N (SiMe3) 2] 2 afforded U (SMes*)[N …

Multiple Bonding Involving the Heavier Main Group 3 Elements

PJ Brothers, PP Power - Adv. Organomet. Chem, 1996 - books.google.com
A. Factors Favoring the Stability of Multiple Bonds to the Heavier Main Group 3 Elements
The chemistry of compounds that involve the heavier main group elements in multiple …

Donor-free alkali metal thiolates: synthesis and structure of dimeric, trimeric, and tetrameric complexes with sterically encumbered terphenyl substituents

M Niemeyer, PP Power - Inorganic chemistry, 1996 - ACS Publications
The synthesis and characterization of the tetrameric lithium thiolate (LiSC6H2-2, 4, 6-Ph3)
4⊙ C7H8 (1), the trimeric lithium thiolate (LiSC6H3-2, 6-Mes2) 3⊙ C6H14 (2)(Mes= 2, 4, 6 …

Complexes of sterically hindered thiolate ligands

JR Dilworth, J Hu - Advances in inorganic chemistry, 1993 - Elsevier
Publisher Summary This chapter discusses the chemistry of sterically hindered thiolate
complexes. The chapter presents a survey that covers the chemistry of transition metal and …

Neutral, three-coordinate, chelating diamide aluminum complexes: catalysts/initiators for synthesis of telechelic oligomers and high polymers

D Chakraborty, EYX Chen - Organometallics, 2002 - ACS Publications
Reaction of the bulky chelating diamine ligand ArNH (CH2) 3NHAr (Ar= 2, 6-iPr2C6H3) with
AlMe3 cleanly affords the monomeric, three-coordinate, chelating diamide aluminum …

The Gallium (III) and Indium (III) Complexes of Tris (2-mercaptobenzyl) amine and Tris (2-hydroxybenzyl) amine

RJ Motekaitis, AE Martell, SA Koch, Hwang… - Inorganic …, 1998 - ACS Publications
Tris (2-mercaptobenzyl) amine, S3N, and tris (2-hydroxybenzyl) amine, O3N, were
investigated with In3+ and Ga3+ in solution and in the solid state to help interpret the …