Cooperative E–H (E= B, Si) bond activations employing κ2-N, S-chelated ruthenium borate
species,[PPh3 {κ2-N, S-(NS2C7H4)} Ru {κ3-H, S, S′-H2B (NC7H4S2) 2}],(1) are …

The recent developments in the field of transition metal (TM) borate complexes have been a
landmark in modern coordination chemistry. The structural diversities of these complexes …

A series of new bis (σ) borate and agostic complexes of group 7 metals have been
synthesized and structurally characterized from various borate ligands, such as trihydrobis …

Building upon previous work, the chemistry of [(η6‐p‐cymene) Ru {P (OMe) 2OR} Cl2],(R= H
or Me) has been extended with [H2B (mbz) 2]−(mbz= 2‐mercaptobenzothiazolyl) using …

The synthesis and reactivity of ruthenium complexes containing an anionic boron based
ligand, supported by mercapto-benzothiazolyl heterocycles are presented. Specifically, the …

The borane adduct of the 2-(methylamido) pyridine anion,[mapyBH3]−, has been
incorporated into octahedral metal complexes. In fac-[Mn (κ3N, H, H-mapyBH3)(CO) 3](1) …

Thermolysis of [(Cp* Nb) 2 (B2H6) 2], 1b (Cp*= η5-C5Me5), with 2-mercaptobenzothiazole,
C6H4NSCSH (MBT), and 2-mercaptobenzoxazole, C6H4NOCSH (MBO), yielded hydrogen …

Electronic structure, vibrational and NMR spectra of metal-Pillarplex (metal= Cu, Ag and Au)
and its inclusion complex with 1, 8-diaminooctane (DAO) are investigated by using density …

An iron pincer complex containing a hemi‐labile (R3P) 2BH2 group exhibits temperature‐
switchable reactivity patterns: a reversible B− H activation concomitant with a P− B bond …

The complexes [Ag {κ3‐S, S′, H‐H2B (mbz) 2}(PR3)] x,(1: x= 2, R= Ph; 2: x= 1, R=
Cy)(mbz= 2‐mercaptobenzothiazolyl) and amidine based dihydro (2‐mercaptobenzo …