Hydroxylamines and their derivatives have found a wide range of applications in organic
synthesis. 1 In this review we hope to cover the synthetic applications of N …

The CO2-involved synthesis of chemicals is of significance. In this work, we found that 1-
alkyl-3-methylimidazolium ionic liquids (ILs) had high efficiency for catalyzing the formylation …

The Schmidt reaction has been an efficient and widely used synthetic approach to amides
and nitriles since its discovery in 1923. However, its application often entails the use of …

The direct synthesis of amides and nitriles from readily available aldehyde precursors
provides access to functional groups of major synthetic utility. To date, most reliable catalytic …

The classical form of the Schmidt reaction involves the reaction of a carbon‐centered
electrophile with hydrazoic acid with loss of nitrogen, usually with a rearrangement that …

The treatment of secondary amines with chloroform in the presence of KF-Al 2 O 3 in
acetonitrile brought about highly facile and efficient N-formylation to give the corresponding …

N-Methylformanilide (MFA) reacts with various electron-rich alkenes in POCl3 solution to
give N-methylquinolinium salts generally in good yield The alkenes can be vinyl acetate, an …

An oxidative rearrangement reaction of spiro tetrahydroisoquinolines has been developed
for the synthesis of fused tetrahydroisoquinolines using in situ generated N-chloroamines …

Fourteen N-and/or 2-substituted 4-fluoroanilines were prepared (the series includes N–C2-
bridged compounds). Some of them were found to be thermally unstable when dissolved in …

Rates of thermal decomposition of title compounds have been measured using a static
reaction system. They undergo a unimolecular first‐order elimination to give arylnitrile and …