Nanomaterials: A review of synthesis methods, properties, recent progress, and challenges

N Baig, I Kammakakam, W Falath - Materials advances, 2021 - pubs.rsc.org
Nanomaterials have emerged as an amazing class of materials that consists of a broad
spectrum of examples with at least one dimension in the range of 1 to 100 nm. Exceptionally …

Endohedral fullerenes

AA Popov, S Yang, L Dunsch - Chemical reviews, 2013 - ACS Publications
One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …

When metal clusters meet carbon cages: endohedral clusterfullerenes

S Yang, T Wei, F Jin - Chemical society reviews, 2017 - pubs.rsc.org
Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …

Current status and future developments of endohedral metallofullerenes

X Lu, L Feng, T Akasaka, S Nagase - Chemical Society Reviews, 2012 - pubs.rsc.org
Endohedral metallofullerenes (EMFs), a new class of hybrid molecules formed by
encapsulation of metallic species inside fullerene cages, exhibit unique properties that differ …

Endohedral metallofullerenes: a unique host–guest association

A Rodríguez-Fortea, AL Balch, JM Poblet - Chemical Society Reviews, 2011 - pubs.rsc.org
In this tutorial review taking X-ray crystallographically characterized compounds as a starting
point a walk is taken through the electronic and structural properties of endohedral …

Chemical, electrochemical, and structural properties of endohedral metallofullerenes

MN Chaur, F Melin, AL Ortiz… - Angewandte Chemie …, 2009 - Wiley Online Library
Ever since the first experimental evidence of the existence of endohedral metallofullerenes
(EMFs) was obtained, the search for carbon cages with encapsulated metals and small …

Two Metastable Endohedral Metallofullerenes Sc2C2@C1(39656)-C82 and Sc2C2@C1(51383)-C84: Direct-C2-Insertion Products from Their Most …

YR Yao, ZC Chen, L Chen, SY Zheng… - Journal of the …, 2023 - ACS Publications
Endohedral metallofullerenes (EMFs) are sub-nano carbon materials with diverse
applications, yet their formation mechanism, particularly for metastable isomers, remains …

The stabilization of fused-pentagon fullerene molecules

YZ Tan, SY Xie, RB Huang, LS Zheng - Nature chemistry, 2009 - nature.com
The isolated pentagon rule (IPR) is now widely accepted as a general rule for determining
the stability of all-carbon fullerene cages composed of hexagons and pentagons. Fullerenes …

Manufacturing of electrochemical sensors via carbon nanomaterials novel applications: a systematic review

S Bagyalakshmi, A Sivakami, K Pal… - Journal of Nanoparticle …, 2022 - Springer
Most significant optical, mechanical, thermal, electronic, and chemical properties of carbon
nanomaterials assist to fabricate the best electrochemical sensors with enhanced …

Trimetallic nitride template endohedral metallofullerenes: discovery, structural characterization, reactivity, and applications

J Zhang, S Stevenson, HC Dorn - Accounts of chemical research, 2013 - ACS Publications
Shortly after the discovery of the carbon fullerene allotrope, C60, researchers recognized
that the hollow spheroidal shape could accommodate metal atoms, or clusters, which quickly …