Overriding Cage Effect in Electron Donor‐Acceptor Photoactivation of Diaryliodonium Reagents: Synthesis of Chalcogenides

P Meher, SK Parida, SK Mahapatra… - … A European Journal, 2024 - Wiley Online Library
In recent times, diaryliodonium reagents (DAIRs) have witnessed a resurgence as arylating
reagents, especially under photoinduced conditions. However, reactions proceeding …

N–H Insertion of Anilines on N-Tosylhydrazones Induced by Visible Light Irradiation

C Faure, S Benmaouche, P Belmont… - The Journal of …, 2024 - ACS Publications
Diazo compounds and their precursors represent an interesting chemical category for
organic synthesis. Particularly, N-tosylhydrazones have attracted attention for their easy …

Catalyst-free photoinduced C(sp3)-C(sp3) bond formation through CH insertions using non-activated alkanes/ethers

Q Li, D Wang, J Wang, L Zhang, X Xu, X Han… - Science China …, 2024 - Springer
Among the various strategies to achieve C (sp3)-C (sp3) bond formation, the direct
application of alkanes and ethers as coupling partners is an emerging and appealing …

Visible-Light-Induced [4+ 3]-Annulation of Carbonyl Ylides with Alkenyl Pyrazolinone for Constructing [4.2. 1]-Oxo-Bridged Oxocine Skeleton

DS Ji, X Zhang, P Zhang, X Bao, Y Yuan, C Huo… - Organic …, 2025 - ACS Publications
Herein, we present a visible-light-induced protocol for the synthesis of highly functionalized
oxo-bridged oxocine skeletons. This method generates carbenes via visible-light-induced …

Access to Diverse Carbonyl Compounds by Catalyst‐Free and Photoinduced Aerobic Cleavage of C= N Bonds

D Xia, W Wang, X Xu, Y Zhu, Q Li… - … A European Journal, 2024 - Wiley Online Library
Functional group interconversion is of great significance in organic synthesis. However,
aerobic cleavage of C= N bonds to access carbonyl compounds still suffered from some …

Visible-light-mediated catalyst-free synthesis of trifluoromethyl (spiro)-epoxides bearing contiguous quaternary centers

J Lin, Y Zhang, J Wang, X Han, S Zhu, T Li… - Organic Chemistry …, 2024 - pubs.rsc.org
Epoxides are regarded as important pharmacophores that can have a huge effect on
improving drug activity. However, epoxides with continuous quaternary centers are …

[PDF][PDF] Facile Access to Hindered Ethers via Photoinduced OH Bond Insertions

Y Zhang, X Han, D Li, D Wang, J Wang, X Luan, SF Ni… - 2024 - chemrxiv.org
The synthesis of the hindered and polyfluorinated dialkyl ethers poses challenges owing to
the bulkiness of tertiary alcohols and the low nucleophilicity of polyfluorinated alcohols …

Light‐Induced Transformations of Donor‐Donor Diazo Compounds Derived from N‐Sulfonylhydrazones

P Yamini, M Junaid, D Yadagiri - Chemistry–An Asian Journal - Wiley Online Library
The donor‐donor carbene chemistry field is underdeveloped and often relies on harsh
reaction conditions, utilizing either thermal or oxidative process with or without transition …