After conquering the atomic structure about a century ago, chemists have been largely
interested in understanding the concept of chemical bond and the formation of a molecule …

Since uranium has several common paramagnetic oxidation states, ie, 5f 1 U5+, 5f 2 U4+,
and 5f 3 U3+, one of the analytical methods commonly used for characterizing uranium …

Molecular nitrogen (N2) is cheap and widely available, but its unreactive nature is a
challenge when attempting to functionalize it under mild conditions with other widely …

Actinide chemistry is gaining increased focus in modern research, particularly in the fields of
energy research and molecular magnetism. However, the structure–function and structure …

Two‐electron oxidative addition is one of the most important elementary reactions for d‐
block transition metals but it is uncommon for f‐block elements. Here, we report the first …

Energetically efficient electrocatalysts with high product selectivity are desirable targets for
sustainable chemical fuel generation using renewable electricity. Recycling CO2 by …

The activation and functionalization of carbon dioxide entails great interest related to its
abundance, low toxicity and associated environmental problems. However, the inertness of …

Herein, we report the redox reactivity of a multimetallic uranium complex supported by
triphenylsiloxide (− OSiPh3) ligands, where we show that low valent synthons can be …

The gaseous small molecules, CO2 and N2O, play important roles in climate change and
ozone layer depletion, and they hold promise as underutilized reagents and chemical …

The direct activation of C–H bonds has been a rich and active field of organometallic
chemistry for many years. Recently, incredible progress has been made and important …