First glycine isomer detected in the interstellar medium: glycolamide (NH2C (O) CH2OH)

VM Rivilla, M Sanz-Novo, I Jiménez-Serra… - The Astrophysical …, 2023 - iopscience.iop.org
We report the first detection in the interstellar medium (ISM) of a C 2 H 5 O 2 N isomer: syn-
glycolamide (NH 2 C (O) CH 2 OH). The exquisite sensitivity at sub-mK levels of an …

Understanding (coupled) large amplitude motions: the interplay of microwave spectroscopy, spectral modeling, and quantum chemistry

HVL Nguyen, I Kleiner - Physical Sciences Reviews, 2022 - degruyter.com
A large variety of molecules contain large amplitude motions (LAMs), inter alia internal
rotation and inversion tunneling, resulting in tunneling splittings in their rotational spectrum …

Asymmetric-top molecules containing one methyl-like internal rotor: Methods and codes for fitting and predicting spectra

I Kleiner - Journal of Molecular Spectroscopy, 2010 - Elsevier
This paper is a review of various effective Hamiltonians, methods and codes dealing with
asymmetric-top molecules containing one internal rotor with C3v (or close to C3v) symmetry …

Laboratory spectroscopic study of isotopic thioformaldehyde, H2CS, and determination of its equilibrium structure

HSP Müller, A Maeda, S Thorwirth, F Lewen… - Astronomy & …, 2019 - aanda.org
Context. Thioformaldehyde is an abundant molecule in various regions of the interstellar
medium. However, available laboratory data limit the accuracies of calculated transition …

Determination of precise relative energies of conformers of n-propanol by rotational spectroscopy

Z Kisiel, O Dorosh, A Maeda, IR Medvedev… - Physical Chemistry …, 2010 - pubs.rsc.org
The rotational spectrum of n-propanol (n-CH3CH2CH2OH) was studied with several
techniques of contemporary broadband rotational spectroscopy at frequencies from 8 to 550 …

Submillimeter wave spectrum of acetic acid

VV Ilyushin, CP Endres, F Lewen, S Schlemmer… - Journal of Molecular …, 2013 - Elsevier
We present a new global study of the submillimeter wave spectrum of the lowest three
torsional states of acetic acid (CH 3 COOH). New measurements involving torsion–rotation …

13C–METHYL FORMATE: OBSERVATIONS OF A SAMPLE OF HIGH-MASS STAR-FORMING REGIONS INCLUDING ORION–KL AND SPECTROSCOPIC …

C Favre, M Carvajal, D Field… - The Astrophysical …, 2014 - iopscience.iop.org
We have surveyed a sample of massive star-forming regions located over a range of
distances from the Galactic center for methyl formate, HCOOCH 3, and its isotopologues H …

Millimetre-wave laboratory study of glycinamide and a search for it with ALMA towards Sagittarius B2 (N)

Z Kisiel, L Kolesniková, A Belloche… - Astronomy & …, 2022 - aanda.org
Context. Glycinamide (NH 2 CH 2 C (O) NH 2) is considered to be one of the possible
precursors of the simplest amino acid, glycine. Its only rotational spectrum reported so far …

Laboratory detection and astronomical study of interstellar acetohydroxamic acid, a glycine isomer

M Sanz-Novo, JL Alonso, VM Rivilla… - Astronomy & …, 2022 - aanda.org
Aims. In this work, we aim to achieve the first laboratory detection of acetohydroxamic acid
(CH 3 CONHOH), a relevant glycine isomer, to enable its eventual identification in the ISM …

Spectroscopy of interstellar internal rotors: an important tool for investigating interstellar chemistry

I Kleiner - ACS Earth and Space Chemistry, 2019 - ACS Publications
This paper is a review of molecules with internal rotors detected or tentatively detected with
upper limits in the interstellar medium. Internal rotor molecules containing one or two methyl …