A large variety of molecules contain large amplitude motions (LAMs), inter alia internal rotation and inversion tunneling, resulting in tunneling splittings in their rotational spectrum …
I Kleiner - Journal of Molecular Spectroscopy, 2010 - Elsevier
This paper is a review of various effective Hamiltonians, methods and codes dealing with asymmetric-top molecules containing one internal rotor with C3v (or close to C3v) symmetry …
HSP Müller, A Maeda, S Thorwirth, F Lewen… - Astronomy & …, 2019 - aanda.org
Context. Thioformaldehyde is an abundant molecule in various regions of the interstellar medium. However, available laboratory data limit the accuracies of calculated transition …
Z Kisiel, O Dorosh, A Maeda, IR Medvedev… - Physical Chemistry …, 2010 - pubs.rsc.org
The rotational spectrum of n-propanol (n-CH3CH2CH2OH) was studied with several techniques of contemporary broadband rotational spectroscopy at frequencies from 8 to 550 …
We present a new global study of the submillimeter wave spectrum of the lowest three torsional states of acetic acid (CH 3 COOH). New measurements involving torsion–rotation …
We have surveyed a sample of massive star-forming regions located over a range of distances from the Galactic center for methyl formate, HCOOCH 3, and its isotopologues H …
Z Kisiel, L Kolesniková, A Belloche… - Astronomy & …, 2022 - aanda.org
Context. Glycinamide (NH 2 CH 2 C (O) NH 2) is considered to be one of the possible precursors of the simplest amino acid, glycine. Its only rotational spectrum reported so far …
Aims. In this work, we aim to achieve the first laboratory detection of acetohydroxamic acid (CH 3 CONHOH), a relevant glycine isomer, to enable its eventual identification in the ISM …
I Kleiner - ACS Earth and Space Chemistry, 2019 - ACS Publications
This paper is a review of molecules with internal rotors detected or tentatively detected with upper limits in the interstellar medium. Internal rotor molecules containing one or two methyl …