Designing artificial metalloenzymes by tuning of the environment beyond the primary coordination sphere

C Van Stappen, Y Deng, Y Liu, H Heidari… - Chemical …, 2022 - ACS Publications
Metalloenzymes catalyze a variety of reactions using a limited number of natural amino
acids and metallocofactors. Therefore, the environment beyond the primary coordination …

Enzymatic processing of lignocellulosic biomass: principles, recent advances and perspectives

H Østby, LD Hansen, SJ Horn… - Journal of Industrial …, 2020 - academic.oup.com
Efficient saccharification of lignocellulosic biomass requires concerted development of a
pretreatment method, an enzyme cocktail and an enzymatic process, all of which are …

Lignocellulose degradation: An overview of fungi and fungal enzymes involved in lignocellulose degradation

M Andlar, T Rezić, N Marđetko… - Engineering in life …, 2018 - Wiley Online Library
This review aims to present current knowledge of the fungi involved in lignocellulose
degradation with an overview of the various classes of lignocellulose‐acting enzymes …

Advances and perspectives on mass transfer and enzymatic hydrolysis in the enzyme-mediated lignocellulosic biorefinery: a review

C Sun, X Meng, F Sun, J Zhang, M Tu, JS Chang… - Biotechnology …, 2023 - Elsevier
Enzymatic hydrolysis is a critical process for the cellulase-mediated lignocellulosic
biorefinery to produce sugar syrups that can be converted into a whole range of biofuels and …

On the expansion of biological functions of lytic polysaccharide monooxygenases

TM Vandhana, JL Reyre, D Sushmaa… - New …, 2022 - Wiley Online Library
Lytic polysaccharide monooxygenases (LPMOs) constitute an enigmatic class of enzymes,
the discovery of which has opened up a new arena of riveting research. LPMOs can …

Kβ X-ray Emission Spectroscopy of Cu(I)-Lytic Polysaccharide Monooxygenase: Direct Observation of the Frontier Molecular Orbital for H2O2 Activation

H Lim, MT Brueggemeyer, WJ Transue… - Journal of the …, 2023 - ACS Publications
Lytic polysaccharide monooxygenases (LPMOs) catalyze the degradation of recalcitrant
carbohydrate polysaccharide substrates. These enzymes are characterized by a …

Oxidoreductases and reactive oxygen species in conversion of lignocellulosic biomass

B Bissaro, A Várnai, ÅK Røhr… - … and Molecular Biology …, 2018 - Am Soc Microbiol
Biomass constitutes an appealing alternative to fossil resources for the production of
materials and energy. The abundance and attractiveness of vegetal biomass come along …

Exploring the partial degradation of polysaccharides: Structure, mechanism, bioactivities, and perspectives

SK Chen, X Wang, YQ Guo, XX Song… - … Reviews in Food …, 2023 - Wiley Online Library
Polysaccharides are promising biomolecules with lowtoxicity and diverse bioactivities in
food processing and clinical drug development. However, an essential prerequisite for their …

Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations

R Trammell, K Rajabimoghadam… - Chemical …, 2019 - ACS Publications
Copper is one of the most abundant and less toxic transition metals. Nature takes advantage
of the bioavailability and rich redox chemistry of Cu to carry out oxygenase and oxidase …

Microbial lignocellulolytic enzymes for the effective valorization of lignocellulosic biomass: a review

P Nargotra, V Sharma, YC Lee, YH Tsai, YC Liu… - Catalysts, 2022 - mdpi.com
The urgent demand for alternative energy sources has been sparked by the tremendous
burden on fossil fuels and the resulting acute energy crisis and climate change issues …