Understanding MOF flexibility: An analysis focused on pillared layer MOFs as a model system

I Senkovska, V Bon, L Abylgazina, M Mendt… - Angewandte …, 2023 - Wiley Online Library
Flexible porous frameworks are at the forefront of materials research. A unique feature is
their ability to open and close their pores in an adaptive manner induced by chemical and …

Solid-state NMR spectroscopy: an advancing tool to analyse the structure and properties of metal–organic frameworks

E Brunner, M Rauche - Chemical Science, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) gain increasing interest due to their outstanding
properties like extremely high porosity, structural variability, and various possibilities for …

Chemistry and potential candidature of metal-organic frameworks for electrochemical energy storage devices

T Mageto, FM de Souza, J Kaur, A Kumar… - Fuel Processing …, 2023 - Elsevier
Conversion and energy storage through electrochemical devices such as batteries and
supercapacitors are crucial in the establishment of sustainable energy. Metal-organic …

Tailoring adsorption induced phase transitions in the pillared-layer type metal–organic framework DUT-8 (Ni)

N Kavoosi, V Bon, I Senkovska, S Krause, C Atzori… - Dalton …, 2017 - pubs.rsc.org
Tailoring the characteristics of gating transitions in the porous network, Ni2 (ndc) 2dabco
(ndc= 2, 6-naphthalenedicarboxylate, dabco= 1, 4-diazabicyclo [2.2. 2] octane), also termed …

Conformational isomerism controls collective flexibility in metal–organic framework DUT-8 (Ni)

PS Petkov, V Bon, CL Hobday, AB Kuc… - Physical Chemistry …, 2019 - pubs.rsc.org
Metal–organic frameworks (MOFs) are coordination networks with organic ligands
containing potential voids. Some MOFs show pronounced structural flexibility that may result …

In Situ 13C NMR Spectroscopy Study of CO2/CH4 Mixture Adsorption by Metal–Organic Frameworks: Does Flexibility Influence Selectivity?

M Sin, N Kavoosi, M Rauche, J Pallmann, S Paasch… - Langmuir, 2019 - ACS Publications
Metal–organic frameworks are promising candidates for selective separation processes
such as CO2 removal from methane (natural gas sweetening). Framework flexibility, that is …

[HTML][HTML] Experimental and theoretical investigations of the electronic band structure of metal-organic frameworks of HKUST-1 type

ZG Gu, L Heinke, C Wöll, T Neumann… - Applied Physics …, 2015 - pubs.aip.org
The electronic properties of metal-organic frameworks (MOFs) are increasingly attracting the
attention due to potential applications in sensor techniques and (micro-) electronic …

Monitoring Dynamics, Structure, and Magnetism of Switchable Metal–Organic Frameworks via 1H‐Detected MAS NMR

J Blahut, AL Lejeune, S Ehrling… - Angewandte Chemie …, 2021 - Wiley Online Library
We present a toolbox for the rapid characterisation of powdered samples of paramagnetic
metal–organic frameworks at natural abundance by 1H‐detected solid‐state NMR. Very fast …

Tailoring the Adsorption-Induced Flexibility of a Pillared Layer Metal–Organic Framework DUT-8 (Ni) by Cobalt Substitution

S Ehrling, M Mendt, I Senkovska, JD Evans… - Chemistry of …, 2020 - ACS Publications
Controlling the adsorption behavior of switchable porous materials is essential to pave the
way for their successful implementation in highly selective separation and sensing …

EPR insights into switchable and rigid derivatives of the metal–organic framework DUT-8 (Ni) by NO adsorption

M Mendt, F Gutt, N Kavoosi, V Bon… - The Journal of …, 2016 - ACS Publications
The metal–organic framework (MOF) DUT-8 (Ni)(DUT= Dresden University of Technology)
shows a structural transformation from a nonporous to a porous phase during the adsorption …