Rongalite: a useful green reagent in organic synthesis

S Kotha, P Khedkar - Chemical Reviews, 2012 - ACS Publications
Rongalite, also called Rongalit (Rongal-registered trademark of BASF), is sodium
hydroxymethanesulfinate dihydrate, which is represented by the chemical formula …

Ring opening reactions of heterocycles with selenium and tellurium nucleophiles

D Tanini, A Capperucci - New Journal of Chemistry, 2019 - pubs.rsc.org
An overview of the preparation and synthetic potentialities of functionalized organoselenium
and organotellurium compounds is presented. Various methods to generate selenated or …

Silver‐Catalyzed One‐Pot Three‐Component Selective Synthesis of β‐Hydroxy Selenides

T Leng, G Wu, YB Zhou, W Gao, J Ding… - Advanced Synthesis …, 2018 - Wiley Online Library
A convenient, multi‐component reaction of organoboronic acids, selenium powder and
epoxides has been developed, providing an efficient protocol for the synthesis of β‐hydroxy …

Visible‐Light‐Induced Hydroxysulfurization and Alkoxysulfurization of Styrenes in the Absence of Photocatalyst: Synthesis of β‐Hydroxysulfides and β‐Alkoxysulfides

H Ruan, LG Meng, L Zhu… - Advanced Synthesis & …, 2019 - Wiley Online Library
We developed hydroxysulfurization and alkoxysulfurization of styrenes using a visible‐light
synthetic strategy in the absence of photocatalyst and oxidant. This strategy provided the …

Synthesis of novel selenides bearing benzenesulfonamide moieties as carbonic anhydrase I, II, IV, VII, and IX inhibitors

A Angeli, D Tanini, A Capperucci… - ACS Medicinal …, 2017 - ACS Publications
A series of novel selenides bearing benzenesulfonamide moieties was synthesized and
investigated for the inhibition of five human (h) isoforms of zinc enzyme carbonic anhydrase …

Recent Developments in Rongalite Chemistry: A Critical Review

R Ali - ChemistrySelect, 2023 - Wiley Online Library
Rongalite whose chemical structure was discovered in 1905, is an inexpensive, easily
assessable, and copious industrial product, which has significantly been used for a long …

Electrochemical selenofunctionalization of unactivated alkenes: access to β-hydroxy-selenides

AB Dapkekar, G Satyanarayana - Organic & Biomolecular Chemistry, 2024 - pubs.rsc.org
This work demonstrates the electrochemical construction of 2-methyl-1-aryloxy-3-
(arylselanyl) propan-2-ol/2-hydroxy-2-methyl-3-(arylselanyl) propyl 2-(2-hydroxy-2-methyl-3 …

Rongalite‐Promoted on Water Synthesis of Functionalised Tellurides and Ditellurides

D Tanini, L Ricci, A Capperucci - Advanced Synthesis & …, 2020 - Wiley Online Library
The on water reaction of sodium telluride with electrophiles has been explored. Na2Te,
generated in situ through the rongalite (sodium hydroxymethanesulfinate)‐promoted …

Catalyst and Additive‐Free Selective Ring‐Opening Selenocyanation of Heterocycles with Elemental Selenium and TMSCN

LG Lu, K Bi, XB Huang, MC Liu… - … Synthesis & Catalysis, 2021 - Wiley Online Library
A catalyst and additive‐free strategy for selective ring‐opening selenocyanation of saturated
heterocycles with elemental selenium and TMSCN is developed, affording a series of …

Mild and selective silicon-mediated access to enantioenriched 1, 2-mercaptoamines and β-amino arylchalcogenides

D Tanini, C Borgogni, A Capperucci - New Journal of Chemistry, 2019 - pubs.rsc.org
Metal-free ring opening reactions of activated and unactivated aziridines with different silyl
chalcogenides are described. Judicious tuning of the reaction conditions enables the …