Multicarrier dynamics in quantum dots

C Melnychuk, P Guyot-Sionnest - Chemical Reviews, 2021 - ACS Publications
Multicarrier dynamics play an essential role in quantum dot photophysics and
photochemistry, and they are primarily governed by nonradiative Auger processes. Auger …

Confinement and exciton binding energy effects on hot carrier cooling in lead halide perovskite nanomaterials

BP Carwithen, TR Hopper, Z Ge, N Mondal, T Wang… - ACS …, 2023 - ACS Publications
The relaxation of the above-gap (“hot”) carriers in lead halide perovskites (LHPs) is
important for applications in photovoltaics and offers insights into carrier–carrier and carrier …

Making and Breaking of Exciton Cooling Bottlenecks in Halide Perovskite Nanocrystals

JWM Lim, Y Guo, M Feng, R Cai… - Journal of the American …, 2023 - ACS Publications
Harnessing quantum confinement (QC) effects in semiconductors to retard hot carrier
cooling (HCC) is an attractive approach for enabling efficient hot carrier extraction to …

Free carrier emergence and onset of electron–phonon coupling in methylammonium lead halide perovskite films

T Ghosh, S Aharon, L Etgar… - Journal of the American …, 2017 - ACS Publications
Sub-10 fs resolution pump–probe experiments on methylammonium lead halide perovskite
films are described. Initial response to photoexcitation is assigned to localized hot excitons …

Hot carrier dynamics in perovskite nanocrystal solids: role of the cold carriers, nanoconfinement, and the surface

TR Hopper, A Gorodetsky, A Jeong, F Krieg… - Nano …, 2020 - ACS Publications
Carrier cooling is of widespread interest in the field of semiconductor science. It is linked to
carrier–carrier and carrier–phonon coupling and has profound implications for the …

Probing excitons in ultrathin PbS nanoplatelets with enhanced near-infrared emission

F Manteiga Vázquez, Q Yu, LF Klepzig… - The journal of …, 2021 - ACS Publications
Colloidal PbS nanoplatelets (NPLs) are highly interesting materials for near-infrared
optoelectronic applications. We use ultrafast transient optical absorption spectroscopy to …

Unusually Strong Biexciton Repulsion Detected in Quantum Confined CsPbBr3 Nanocrystals with Two and Three Pulse Femtosecond Spectroscopy

J Dana, T Binyamin, L Etgar, S Ruhman - ACS nano, 2021 - ACS Publications
Transient absorption measurements were conducted on pristine and monoexciton saturated
CsPbBr3 nanocrystals varying in size within the regime of a strong quantum confinement …

Hot Excitons Cool in Metal Halide Perovskite Nanocrystals as Fast as CdSe Nanocrystals

DP Strandell, D Zenatti, P Nagpal, A Ghosh, DN Dirin… - ACS …, 2023 - ACS Publications
The idea of phonon bottlenecks has long been pursued in nanoscale materials for their
application in hot exciton devices, such as photovoltaics. Decades ago, it was shown that …

Subpicosecond Exciton Dynamics and Biexcitonic Feature in Colloidal CuInS2 Nanocrystals: Role of In–Cu Antisite Defects

T Debnath, S Maiti, P Maity… - The Journal of Physical …, 2015 - ACS Publications
Charge carrier dynamics of multinary quantum dots like CuInS2 (CIS) nanocrystals (NCs) is
not clearly understood, especially in ultrafast time scales. Herein we have synthesized …

Spectator Exciton Effects on Nanocrystal Photophysics II: PbS

J Dana, T Ghosh, I Gdor, A Shapiro… - The Journal of …, 2022 - ACS Publications
The spectator exciton method follows stepwise changes in a nanocrystal's absorption with
the accumulated number of excitons. It involves comparison of pump–probe spectra in …