[HTML][HTML] Photofunctionality of iron (III) N-heterocyclic carbenes and related d5 transition metal complexes

P Chábera, L Lindh, NW Rosemann, O Prakash… - Coordination Chemistry …, 2021 - Elsevier
Despite a few reports of photoluminescent and strongly photo-oxidizing transition metal
complexes with ad 5 electronic configuration, the photophysics and photochemistry of this …

Is iron the new ruthenium?

OS Wenger - Chemistry–A European Journal, 2019 - Wiley Online Library
Ruthenium complexes with polypyridine ligands are very popular choices for applications in
photophysics and photochemistry, for example, in lighting, sensing, solar cells, and …

Deuterated molecular ruby with record luminescence quantum yield

C Wang, S Otto, M Dorn, E Kreidt… - Angewandte Chemie …, 2018 - Wiley Online Library
The recently reported luminescent chromium (III) complex 13+([Cr (ddpd) 2] 3+; ddpd= N,
N′‐dimethyl‐N, N′‐dipyridine‐2‐yl‐pyridine‐2, 6‐diamine) shows exceptionally strong …

A strongly luminescent chromium (III) complex acid

S Otto, C Förster, C Wang… - … A European Journal, 2018 - Wiley Online Library
The synthesis, structure, reactivity, and photophysical properties of a novel acidic,
luminescent chromium (III) complex [Cr (H2tpda) 2] 3+(23+) bearing the tridentate H2tpda (2 …

Mechanistic and Kinetic Investigations of ON/OFF (Photo) Switchable Binding of Carbon Monoxide by Chromium (0), Molybdenum (0) and Tungsten (0) Carbonyl …

PJ Boden, P Di Martino‐Fumo, T Bens… - … A European Journal, 2022 - Wiley Online Library
This work tackles the photochemistry of a series of mononuclear Cr0, Mo0 and W0 carbonyl
complexes containing a bidentate mesoionic carbene ligand of the 1, 2, 3‐triazol‐5‐ylidene …

Mesoionic Imines (MIIs): Strong Donors and Versatile Ligands for Transition Metals and Main Group Substrates

R Rudolf, NI Neuman, RRM Walter… - Angewandte Chemie …, 2022 - Wiley Online Library
We report the synthesis and the reactivity of 1, 2, 3‐triazolin‐5‐imine type mesoionic imines
(MIIs). The MIIs are accessible by a base‐mediated cycloaddition between a substituted …

Protic NNN and NCN Pincer‐Type Ruthenium Complexes Featuring (Trifluoromethyl) pyrazole Arms: Synthesis and Application to Catalytic Hydrogen Evolution from …

Y Nakahara, T Toda, A Matsunami… - Chemistry–An Asian …, 2018 - Wiley Online Library
NNN and NCN pincer‐type ruthenium (II) complexes featuring two protic pyrazol‐3‐yl arms
with a trifluoromethyl (CF3) group at the 5‐position were synthesized and structurally …

Isomerization Reactions in Anionic Mesoionic Carbene‐Borates and Control of Properties and Reactivities in the Resulting CoII Complexes through Agostic …

J Stubbe, NI Neuman, R McLellan… - Angewandte Chemie …, 2021 - Wiley Online Library
We present herein anionic borate‐based bi‐mesoionic carbene compounds of the 1, 2, 3‐
triazol‐4‐ylidene type that undergo C− N isomerization reactions. The isomerized …

Mesoionic 1,2,3‐Triazolo[1,5‐a]pyridine‐3‐ylidenes in Phosphorescent Platinum(II) Complexes

J Soellner, T Strassner - ChemPhotoChem, 2019 - Wiley Online Library
Mesoionic carbene ligands based on 1, 2, 3‐triazole platforms can be used in
cyclometalated platinum (II) complexes to achieve an efficient phosphorescence even at …

Isomerisierungsreaktionen in anionischen mesoionischen Carbenboraten und Kontrolle der Eigenschaften und Reaktivität in den entstehenden CoII‐Komplexen …

J Stubbe, NI Neuman, R McLellan… - Angewandte …, 2021 - Wiley Online Library
Wir präsentieren anionische Borat‐basierte bi‐mesoionische Carbenverbindungen vom Typ
1, 2, 3‐Triazol‐4‐yliden, die C‐N‐Isomerisierungen eingehen können. Die isomerisierten …