The large carbon footprint of the Haber–Bosch process, which provides ammonia for
fertilizers but also the feedstock for all nitrogenous commercial products, has fueled the …

The functionalization of coordinated dinitrogen to form nitrogen–element bonds en route to
nitrogen-containing molecules is a long-standing challenge in chemical synthesis. The …

Activation of dinitrogen plays an important role in daily anthropogenic life, and the processes
by which this fixation occurs have been a longstanding and significant research focus within …

Molecular nitrogen (N2) is the most abundant gas in Earth's atmosphere, but its low reactivity
has hampered its use as a precursor to higher value nitrogen-containing compounds …

This paper describes a recent advance on the conversion of molecular dinitrogen into
ammonia or ammonia equivalent, silylamine, by using transition metal–dinitrogen …

Hydrosilanes are used as versatile coreactants in the generation of silyl-metal complexes.
Since organohydrosilanes may contain one, two, or three SiH bonds as tertiary, secondary …

Dinitrogen (N2) is the most abundant gas in Earth's atmosphere, but its inertness hinders its
use as a nitrogen source in the biosphere and in industry. Efficient catalysts are hence …

Transition-metal complexes of O2 and N2 play an important role in the environment,
chemical industry, and metalloenzymes. This Perspective compares and contrasts the …

[ReCl3 (PPh3) 2 (NCMe)] reacts with pincer ligand HN (CH2CH2P t Bu2) 2 (H PNP) to five
coordinate rhenium (III) complex [ReCl2 (PNP)]. This compound cleaves N2 upon reduction …

Electron-rich organosilicon compounds, such as 1, 4-bis (trimethylsilyl)-1, 4-diaza-2, 5-
cyclohexadiene (2a), 2, 5-dimethyl-1, 4-bis (trimethylsilyl)-1, 4-diaza-2, 5-cyclohexadiene …