Visible-to-NIR-light activated release: from small molecules to nanomaterials

R Weinstain, T Slanina, D Kand, P Klan - Chemical reviews, 2020 - ACS Publications
Photoactivatable (alternatively, photoremovable, photoreleasable, or photocleavable)
protecting groups (PPGs), also known as caged or photocaged compounds, are used to …

Electro-and solar-driven fuel synthesis with first row transition metal complexes

KE Dalle, J Warnan, JJ Leung, B Reuillard… - Chemical …, 2019 - ACS Publications
The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

Mechanistic aspects of CO2 reduction catalysis with manganese-based molecular catalysts

DC Grills, MZ Ertem, M McKinnon, KT Ngo… - Coordination Chemistry …, 2018 - Elsevier
One approach for the conversion of CO 2 into fuels or fuel precursors is the proton-coupled
reduction of CO 2 to CO or formic acid, using transition metal complexes as catalysts in …

PhotoCORMs: CO release moves into the visible

MA Wright, JA Wright - Dalton Transactions, 2016 - pubs.rsc.org
The potential of carbon monoxide to act as a therapeutic agent is now well-established.
Controlled delivery of CO is best achieved using 'CORMs': molecules which release known …

Structure–photoreactivity relationship of 3-hydroxyflavone-based CO-releasing molecules

M Russo, V Orel, P Stacko, M Srankova… - The Journal of …, 2022 - ACS Publications
Carbon monoxide (CO) is an endogenous signaling molecule that regulates diverse
physiological processes. The therapeutic potential of CO is hampered by its intrinsic toxicity …

Red-light activated photoCORMs of Mn (I) species bearing electron deficient 2, 2′-azopyridines

E Kottelat, A Ruggi, F Zobi - Dalton Transactions, 2016 - pubs.rsc.org
The realization of CO releasing molecules triggered by light (photoCORMs) within the
phototherapeutic window (λ> 600 nm) constitutes an important goal for potential therapeutic …

Visible light-activated photoCORMs

E Kottelat, F Zobi - Inorganics, 2017 - mdpi.com
Despite its well-known toxicity, carbon monoxide (CO) is now recognized as a potential
therapeutic agent. Its inherent toxicity, however, has limited clinical applications because …

Manganese N‐Heterocyclic Carbene Complexes for Catalytic Reduction of Ketones with Silanes

M Pinto, S Friães, F Franco, J Lloret‐Fillol… - …, 2018 - Wiley Online Library
Well‐defined manganese (I) carbonyl complexes bearing bis‐N‐heterocyclic carbene
(NHC) ligands are shown to be effective catalysts for the reduction of carbonyl groups …

Exceptionally rapid CO release from a manganese (I) tricarbonyl complex derived from bis (4-chloro-phenylimino) acenaphthene upon exposure to visible light

SJ Carrington, I Chakraborty, PK Mascharak - Dalton Transactions, 2015 - pubs.rsc.org
Two manganese (I) carbonyl complexes derived from α, α′-diimine ligands with extended
conjugated framework namely [MnBr (CO) 3 (BIAN)](1) and [MnBr (CO) 3 (MIAN)](2), have …

Mechanisms of orthogonal photodecarbonylation reactions of 3-hydroxyflavone-based acid–base forms

M Russo, P Štacko, D Nachtigallová… - The Journal of Organic …, 2020 - ACS Publications
Carbon monoxide is a naturally occurring gasotransmitter combining inherent toxicity with a
remarkable therapeutic potential and arduous administration. Photoactivatable carbon …