Conspectus Transition metal hydride catalyzed functionalization of remote and proximal
olefins has many advantages over conventional cross-coupling reactions. It avoids the …

One-pot reactions elaborated around transition metal-catalyzed isomerization of alkenes not
only offer the inherent advantages of atom-, step-and redox-economy but also enable the …

Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …

Ring structures such as pyridine, cyclopentane or their combinations are important motifs in
bioactive molecules. In contrast to previous cycloaddition reactions that necessitated a …

A site-selective defluorinative sp3 C–H alkylation of secondary amides that rapidly and
reliably incorporates gem-difluoroalkene motifs into previously unfunctionalized sp3 sites is …

Site-and enantio-selective alkyl–alkyl bond formation is privileged in the retrosynthetic
analysis due to the universality of sp3-hybridized carbon atoms in organic molecules …

Transformation of sterically hindered tertiary alkyl electrophiles under nickel-catalyzed
conditions to forge C (sp3)–C bonds and simultaneously create challenging all-carbon …

Design of ligands in transition-metal catalyzed reactions is challenging, especially in
asymmetric transformations. With each step in the catalytic cycle promoted by its privileged …

Regiodivergent alkene functionalization that produces either regioisomer starting from the
same raw materials is desirable. Herein, we report a nickel‐catalyzed switchable site …

A mild and regiodivergent aminoalkylation of unactivated alkyl halides is disclosed via a
dual photoredox/nickel catalysis. Bipyridyl-type ligands without an ortho-substituent control …