Organoselenium chemistry: role of intramolecular interactions

AJ Mukherjee, SS Zade, HB Singh, RB Sunoj - Chemical Reviews, 2010 - ACS Publications
In 1836 the first organoselenium compound, diethyl selenide, was prepared by Löwig, 1 and
it was isolated in the pure form in 1869. 2 Early selenium chemistry involved the synthesis of …

Organoselenium ligands in catalysis

A Kumar, GK Rao, F Saleem, AK Singh - Dalton Transactions, 2012 - pubs.rsc.org
Organoselenium ligands are building blocks of several transition metal complexes which
catalyze various organic reactions efficiently in solution. In this review the survey of …

Some highlights from the development and use of bulky monodentate ligands

PP Power - Journal of organometallic chemistry, 2004 - Elsevier
The development of bulky monodentate alkoxide, chalcogenolate (ER, E= S, Se or Te),
amide, pnictide (ER2= N, P, As), alkyl, aryl and silyl ligands is briefly surveyed. These …

The recovery and separation of lithium by using solvent extraction methods

T Kanagasundaram, O Murphy, MN Haji… - Coordination Chemistry …, 2024 - Elsevier
Lithium, the lightest alkali metal, has been called the “new white gold” because of its limited
availability and critical importance in arising applications in clean energy, like hybrid and …

Low-Coordinate Magnesium Sulfide and Selenide Complexes

S Burnett, R Ferns, DB Cordes, AMZ Slawin… - Inorganic …, 2023 - ACS Publications
The reactions of [{(iPrDipNacNac) Mg} 2] 1 (iPrDipnacnac= HC (iPrCNDip) 2) with Ph3P═ O
at 100° C afforded the phosphinate complex [(iPrDipNacNac) Mg (OPPh3)(OPPh2)] 3 …

Coordination of halide and chalcogenolate anions to heavier 1, 2, 5-chalcogenadiazoles: experiment and theory

NA Semenov, AV Lonchakov, NA Pushkarevsky… - …, 2014 - ACS Publications
New products of coordination of anions X–(X= F, I, PhS) to the Te atom of 3, 4-dicyano-1, 2,
5-telluradiazole (1) were synthesized in high yields and characterized by X-ray diffraction …

Chalcogenated Schiff base ligands utilized for metal ion detection

P Kaswan - Inorganica Chimica Acta, 2023 - Elsevier
Metal poisoning has recently arisen as a global concern, which imposes a significant threat
to both the environment and human health. Schiff bases and related metal ion complexes …

s-Block organometallics: Analysis of ion-association and noncovalent interactions on structure and function in benzyl-based compounds

A Torvisco, K Ruhlandt-Senge - Inorganic Chemistry, 2011 - ACS Publications
The organometallic chemistry of alkali and alkaline-earth metals has been marred by
synthetic setbacks because of their high reactivity. Advances in their synthesis and a better …

More arrows in the quiver: New pathways and old problems with heavy alkaline earth metal diphenylmethanides

JS Alexander, K Ruhlandt‐Senge - Chemistry–A European …, 2004 - Wiley Online Library
Progress in the field of σ‐bonded alkaline earth organometallics has been handicapped by
numerous complications, such as high reactivity, low solubility, and the limited availability of …

Palladium (II) complex of an organotellurium ligand as a catalyst for Suzuki Miyaura coupling: Generation and role of nano-sized Pd3Te2

GK Rao, A Kumar, MP Singh, AK Singh - Journal of Organometallic …, 2014 - Elsevier
Abstract Organotellurium ligand (L=(C 6 H 5)(2-HOC 6 H 4) CHNH (CH 2) 3 Te–C 6 H 4− 4−
OMe) and its palladium complex [PdCl (L− H)](1) have been synthesized and characterized …