Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

Conspectus Titanium is an attractive metal for catalytic reaction development: it is earth-
abundant, inexpensive, and generally nontoxic. However—like most early transition metals …

We describe a combined synthetic, spectroscopic, and computational study of a chiral
titanocene complex as a regiodivergent photoredox catalyst (PRC). With Kagan's complex …

We describe a titanocene (III)‐catalyzed deuterosilylation of epoxides that provides β‐
deuterated anti‐Markovnikov alcohols with excellent D‐incorporation, in high yield, and …

Here, we describe that polymethylhydrosiloxane (PMHS) is a sustainable terminal reductant
in the titanocene catalyzed hydrosilylation of epoxides. The products formally constitute the …

We describe a highly diastereo‐and enantioselective two‐step formal anti‐Markovnikov
addition of H2O to diastereomeric mixtures of trisubstituted olefins. Our approach overcomes …

Reduction of red bis (cyclopentadienyl) titanium (IV) dichloride (Cp2TiCl2) with manganese
dust in dry THF produces a green solution that turns deep blue upon the addition of traces of …

A method is described for synthesizing succinonitrile derivatives bearing alkyl or aryl
substituents from cyanohydrin derivatives using low-valent titanium. The active species in …

A method of stereodivergent intramolecular ring‐opening arylation of amine‐tethered
epoxides to 3, 4‐disubstituted tetrahydroquinolines has been developed. The tuneable good …

Significant efforts have been made toward developing sustainable reduction reactions of
organic and bioorganic compounds. In these studies, the selection of reagents and solvents …