Two‐Dimensional Supramolecular Polymorphism in Cyanine H‐and J‐Aggregates

L Rubert, HMA Ehmann, B Soberats - Angewandte Chemie, 2024 - Wiley Online Library
We designed a new cyanine dye 1, with two pedant rod‐like groups, capable of forming two
distinct two‐dimensional (2D) supramolecular polymorphs in methylcyclohexane; an H‐type …

A coopetition-driven strategy of parallel/perpendicular aromatic stacking enabling metastable supramolecular polymerization

Z Gao, X Xie, J Zhang, W Yuan, H Yan… - Nature …, 2024 - nature.com
Metastable supramolecular polymerization under kinetic control has recently been
recognized as a closer way to biosystem than thermodynamic process. While impressive …

Enabling Supramolecular Phase Change Materials with High Latent Heat Ability and Recyclability

Y Liao, Z Wei, S Chen, X Zeng, X Chen… - Industrial & …, 2024 - ACS Publications
The design of supramolecular phase change materials (SPCMs) with both high latent heat
and recyclability remains challenging via multivalent interactions such as hydrogen bonds …

Handedness‐Inverted and Stimuli‐Responsive Circularly Polarized Luminescent Nano/Micromaterials Through Pathway‐Dependent Chiral Supramolecular …

C Zhao, Y Wang, Y Jiang, N Wu, H Wang… - Advanced …, 2024 - Wiley Online Library
The precise manipulation of supramolecular polymorphs has been widely applied to control
the morphologies and functions of self‐assemblies, but is rarely utilized for the fabrication of …

Topochemical Polymerization of a Supramolecular Polymer and Prominent Ambipolar Charge-Carrier Mobility

A Nag, RP Paitandi, S Seki, S Ghosh - Macromolecules, 2024 - ACS Publications
This study reports the topochemical polymerization of a supramolecular polymer of the n-
type semiconducting naphthalene-diimide (NDI)-appended diacetylene (DA) building block …

Organoboron Polymorphs with Different Molecular Packing Modes for Optical Waveguides

T Zhao, Y Ma, N Wang, F Liu… - Chemistry–A European …, 2024 - Wiley Online Library
Organoboron compounds offer a new strategy to design optoelectronic materials with high
fluorescence efficiency. In this paper, the organoboron compound B‐BNBP with double B← …

Automatic Orbital Pair Selection for Multilevel Local Coupled-Cluster Based on Orbital Maps

L Lampe, J Neugebauer - Journal of Chemical Theory and …, 2024 - ACS Publications
We present an automatic, orbital-map based orbital-pair selection scheme for multilevel
local coupled-cluster approaches that exploits the locality of chemical reactions by focusing …

Coaxial Helices in Chiral Supramolecular Aggregates from Highly Hindered Chiral Allenes

F Freire, M Lago-Silva, M Fernández-Míguez… - Angewandte Chemie … - Wiley Online Library
Chiral allenes self‐assembly following a cooperative mechanism into a supramolecular
chiral aggregate consisting of two coaxial helices: the internal helix described by the allene …

Interfacing Flexible Design and Social Self-Sorting Enables Comprehensive Control over Photophysical and Self-Assembly Properties of Supramolecular Polymers

N Bäumer, S Yamada, S Ogi, S Yamaguchi - 2024 - chemrxiv.org
Supramolecular self-assembly offers an intriguing approach to construct microarchitectures,
which combine properties of their molecular constituents with dynamic supramolecular …

Tuning the morphology of supramolecular aggregates for nanocarrier‐based drug delivery

X Ji, N Wang, J Wang, Y Huang, T Wang, X Huang… - AIChE Journal - Wiley Online Library
Due to the unique drug delivery mode and specific therapy, nano‐formulations are of
interest for biomedical applications and treating many diseases. However, traditional …