The biologically relevant coordination chemistry of iron and nitric oxide: electronic structure and reactivity
Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …
physiological and pathological events in biology. Metal coordination chemistry, especially …
Synthetic Fe/Cu complexes: toward understanding heme-copper oxidase structure and function
Heme-copper oxidases (HCOs) are terminal enzymes on the mitochondrial or bacterial
respiratory electron transport chain, which utilize a unique heterobinuclear active site to …
respiratory electron transport chain, which utilize a unique heterobinuclear active site to …
Regulating oxygen activity of perovskites to promote NOx oxidation and reduction kinetics
Understanding the adsorption and oxidation of NO on metal oxides is of immense interest to
environmental and atmospheric (bio) chemistry. Here, we show that the surface oxygen …
environmental and atmospheric (bio) chemistry. Here, we show that the surface oxygen …
Synthetic Heme/Copper Assemblies: Toward an Understanding of Cytochrome c Oxidase Interactions with Dioxygen and Nitrogen Oxides
S Hematian, I Garcia-Bosch… - Accounts of chemical …, 2015 - ACS Publications
Conspectus Our long-time niche in synthetic biological inorganic chemistry has been to
design ligands and generate coordination complexes of copper or iron ions or both, those …
design ligands and generate coordination complexes of copper or iron ions or both, those …
Recent progress on exploring µ-oxo bridged binuclear porphyrinoid complexes in catalysis and material science
AB Sorokin - Coordination Chemistry Reviews, 2019 - Elsevier
This review covers recent advances in the preparation, characterization and application of µ-
oxo dimeric complexes with different metals and non-metal and macrocyclic ligands …
oxo dimeric complexes with different metals and non-metal and macrocyclic ligands …
Copper (II) activation of nitrite: Nitrosation of nucleophiles and generation of NO by thiols
S Kundu, WY Kim, JA Bertke… - Journal of the American …, 2017 - ACS Publications
Nitrite (NO2–) and nitroso compounds (E-NO, E= RS, RO, and R2N) in mammalian plasma
and cells serve important roles in nitric oxide (NO) dependent as well as NO independent …
and cells serve important roles in nitric oxide (NO) dependent as well as NO independent …
Acid-induced nitrite reduction of nonheme iron (ii)-nitrite: mimicking biological Fe–NiR reactions
Nitrite reductase (NiR) catalyzes nitrite (NO2−) to nitric oxide (NO) transformation in the
presence of an acid (H+ ions/pH) and serves as a critical step in NO biosynthesis. In addition …
presence of an acid (H+ ions/pH) and serves as a critical step in NO biosynthesis. In addition …
A motif for reversible nitric oxide interactions in metalloenzymes
Nitric oxide (NO) participates in numerous biological processes, such as signalling in the
respiratory system and vasodilation in the cardiovascular system. Many metal-mediated …
respiratory system and vasodilation in the cardiovascular system. Many metal-mediated …
Mechanism of O-atom transfer from nitrite: nitric oxide release at copper (II)
M Stauffer, Z Sakhaei, C Greene, P Ghosh… - Inorganic …, 2021 - ACS Publications
Nitric oxide (NO) is a key signaling molecule in health and disease. While nitrite acts as a
reservoir of NO activity, mechanisms for NO release require further understanding. A series …
reservoir of NO activity, mechanisms for NO release require further understanding. A series …
Nitric oxide release via oxygen atom transfer from nitrite at copper (ii)
Z Sakhaei, S Kundu, JM Donnelly, JA Bertke… - Chemical …, 2017 - pubs.rsc.org
Nitric oxide is a vital signaling molecule that controls blood flow and oxygenation and nitrite
serves as an important reservoir for nitric oxide in biology. While copper containing enzymes …
serves as an important reservoir for nitric oxide in biology. While copper containing enzymes …