Emerging trends in polymerization-induced self-assembly

NJW Penfold, J Yeow, C Boyer, SP Armes - ACS Macro Letters, 2019 - ACS Publications
In this Perspective, we summarize recent progress in polymerization-induced self-assembly
(PISA) for the rational synthesis of block copolymer nanoparticles with various …

Functional nanoparticles through π-conjugated polymer self-assembly

LR MacFarlane, H Shaikh… - Nature Reviews …, 2021 - nature.com
The development of π-conjugated polymers has provided a gateway to a variety of new
functional organic materials reminiscent of inorganic semiconductors. Nanoparticles based …

Revising complex supramolecular polymerization under kinetic and thermodynamic control

J Matern, Y Dorca, L Sánchez… - Angewandte Chemie …, 2019 - Wiley Online Library
Pathway complexity, hierarchical organization, out of equilibrium, and metastable or
kinetically trapped species are common terms widely used in recent, high‐quality …

[HTML][HTML] Emerging applications for living crystallization-driven self-assembly

L MacFarlane, C Zhao, J Cai, H Qiu, I Manners - Chemical Science, 2021 - pubs.rsc.org
The use of crystallization as a tool to control the self-assembly of polymeric and molecular
amphiphiles in solution is attracting growing attention for the creation of non-spherical …

[HTML][HTML] Exploiting the role of nanoparticle shape in enhancing hydrogel adhesive and mechanical properties

MC Arno, M Inam, AC Weems, Z Li, ALA Binch… - Nature …, 2020 - nature.com
The ability to control nanostructure shape and dimensions presents opportunities to design
materials in which their macroscopic properties are dependent upon the nature of the …

Polymerization techniques in polymerization-induced self-assembly (PISA)

C Liu, CY Hong, CY Pan - Polymer Chemistry, 2020 - pubs.rsc.org
The development of controlled/“living” polymerization greatly stimulated the prosperity of the
fabrication and application of block copolymer nano-objects. Controlled/“living” …

Control over differentiation of a metastable supramolecular assembly in one and two dimensions

T Fukui, S Kawai, S Fujinuma, Y Matsushita… - Nature …, 2017 - nature.com
Molecular self-assembly under kinetic control is expected to yield nanostructures that are
inaccessible through the spontaneous thermodynamic process. Moreover, time-dependent …

Polymerization-induced self-assembly of block copolymer nanoparticles via RAFT non-aqueous dispersion polymerization

MJ Derry, LA Fielding, SP Armes - Progress in Polymer Science, 2016 - Elsevier
There is considerable current interest in polymerization-induced self-assembly (PISA) via
reversible addition–fragmentation chain transfer (RAFT) polymerization as a versatile and …

Hierarchical nanomaterials assembled from peptoids and other sequence-defined synthetic polymers

Z Li, B Cai, W Yang, CL Chen - Chemical Reviews, 2021 - ACS Publications
In nature, the self-assembly of sequence-specific biopolymers into hierarchical structures
plays an essential role in the construction of functional biomaterials. To develop synthetic …

Self-assembly of block copolymers

Y Mai, A Eisenberg - Chemical Society Reviews, 2012 - pubs.rsc.org
Block copolymer (BCP) self-assembly has attracted considerable attention for many
decades because it can yield ordered structures in a wide range of morphologies, including …