Selective hydrogenation over supported metal catalysts: from nanoparticles to single atoms

L Zhang, M Zhou, A Wang, T Zhang - Chemical reviews, 2019 - ACS Publications
Selective catalytic hydrogenation has wide applications in both petrochemical and fine
chemical industries, however, it remains challenging when two or multiple functional groups …

Acetylene selective hydrogenation: a technical review on catalytic aspects

M Takht Ravanchi, S Sahebdelfar… - Reviews in Chemical …, 2018 - degruyter.com
The catalytic selective hydrogenation of multiunsaturated hydrocarbons, especially in
pyrolysis products, to corresponding mono-olefins is a widely exploited way for the large …

Photo-thermo semi-hydrogenation of acetylene on Pd1/TiO2 single-atom catalyst

Y Guo, Y Huang, B Zeng, B Han, M Akri, M Shi… - Nature …, 2022 - nature.com
Semi-hydrogenation of acetylene in excess ethylene is a key industrial process for ethylene
purification. Supported Pd catalysts have attracted most attention due to their superior …

Ag alloyed Pd single-atom catalysts for efficient selective hydrogenation of acetylene to ethylene in excess ethylene

GX Pei, XY Liu, A Wang, AF Lee, MA Isaacs, L Li… - Acs …, 2015 - ACS Publications
Semihydrogenation of acetylene in an ethylene-rich stream is an industrially important
process. Conventional supported monometallic Pd catalysts offer high acetylene conversion …

In Situ Surface Structures of PdAg Catalyst and Their Influence on Acetylene Semihydrogenation Revealed by Machine Learning and Experiment

XT Li, L Chen, C Shang, ZP Liu - Journal of the American …, 2021 - ACS Publications
PdAg alloy is an industrial catalyst for acetylene-selective hydrogenation in excess ethene.
While significant efforts have been devoted to increase the selectivity, there has been little …

Integration of bimetallic electronic synergy with oxide site isolation improves the selective hydrogenation of acetylene

F Liu, Y Xia, W Xu, L Cao, Q Guan, Q Gu… - Angewandte Chemie …, 2021 - Wiley Online Library
Semi‐hydrogenation of acetylene to ethylene is an important process to purify ethylene
streams in industry. However, among current approaches reported in the literature, high …

The surface chemistry of metal-based hydrogenation catalysis

F Zaera - ACS Catalysis, 2017 - ACS Publications
The promotion of hydrogenation reactions by transition-metal-based heterogeneous
catalysts was established many decades ago but is still quite common in the chemical …

Rational design of PdAg catalysts for acetylene selective hydrogenation via structural descriptor-based screening strategy

J Wang, H Xu, C Che, J Zhu, D Cheng - ACS Catalysis, 2022 - ACS Publications
Pd-based catalysts are widely used in selective hydrogenation reactions, where the surface
structure has been found as a key factor to improve the yield of the target product. However …

Design of core-Pd/shell-Ag nanocomposite catalyst for selective semihydrogenation of alkynes

T Mitsudome, T Urayama, K Yamazaki, Y Maehara… - ACS …, 2016 - ACS Publications
We designed core-Pd/shell-Ag nanocomposite catalyst (Pd@ Ag) for highly selective
semihydrogenation of alkynes. The construction of the core–shell nanocomposite enables a …

Modified Pd catalysts for the selective hydrogenation of acetylene

WJ Kim, SH Moon - Catalysis today, 2012 - Elsevier
This article reviews our previous studies to develop high performance catalysts for acetylene
hydrogenation. Ethylene selectivity of Pd catalysts in acetylene hydrogenation was improved …