The chemistry of actinide (An) and rare-earth metal (Ln and group 3) complexes featuring
multiple bonding interactions with main-group fragments has witnessed an enormous …

Carbon oxygenates represent an increasingly important class of feedstock in the
development of a sustainable chemical economy. Their catalytic transformation into value …

Neptunium was the first actinide element to be artificially synthesized, yet, compared with its
more famous neighbours uranium and plutonium, is less conspicuously studied. Most …

Developing a better understanding of covalency (or orbital mixing) is of fundamental
importance. Covalency occupies a central role in directing chemical and physical properties …

The study of the redox chemistry of mid‐actinides (U− Pu) has historically relied on cerium
as a model, due to the accessibility of trivalent and tetravalent oxidation states for these ions …

Fifty years have passed since the foundation of organometallic neptunium chemistry, and yet
only a handful of complexes have been reported, and even fewer have been fully …

Organoplutonium chemistry was established in 1965, yet structurally authenticated
plutonium–carbon bonds remain rare being limited to π-bonded carbocycle and σ-bonded …

Despite the burgeoning field of uranium-ligand multiple bonds, analogous complexes
involving other actinides remain scarce. For thorium, under ambient conditions only a few …

Neptunium is an actinide element sourced from anthropogenic production, and, unlike
naturally abundant uranium, its coordination chemistry is not well developed in all …

Structures of 388 neptunium-bearing crystal structures are sorted into an expanded
structural hierarchy and examined. The majority of structures contain Np (V)(149), Np …