The recent progress in copper-catalyzed CN cross-coupling reactions is reviewed.
According to the different compounds containing nitrogen, the nucleophiles are divied into …

2-, 3-and 4-Bromopyridine, along with other brominated electron-deficient arenes, undergo
palladium-catalyzed coupling with ureas of structure RNMeCONHMe. Where R is a chiral, α …

We report a facile, microwave-accelerated, one-pot tandem synthesis of unsymmetrical
ureas via a Curtius rearrangement. In this method, one-pot microwave irradiation of …

The amination of aryl halides in liquid ammonia (LNH3) is catalyzed by a copper (I)
salt/ascorbate system to yield primary aromatic amines in good to excellent yields. The low …

The malignant neoplasm, which is recognized as cancer, is a serious threat to human health
and frequently-occurring disease. Diphenylurea, an important link structure in the design of …

Pyrroloazocine indole alkaloids consisting of eight-membered azacycle fused to pyrrole and
indole units exhibit intriguing pharmacological functions but still pose a synthetic challenge …

A highly chemoselective C–H arylation of phenylureas has been accomplished using dual
palladium–photoredox catalysis at room temperature without any additives, base or external …

We report a mild, convenient, environmentally friendly, and ligand-free synthetic protocol for
the cross-coupling reaction of aryl iodides and thiols using 10mol% CuI with KF/Al2O3 as …

CuI/N-methylglycine-catalyzed coupling reaction of guanidine nitrate with both aryl iodides
and bromides takes place at 70–100° C, affording symmetrical N, N′-diaryl guanidines with …

This report describes an unprecedented protocol for the synthesis of N, N′-substituted
ureas using a cross-coupling method. Mono substituted ureas were modified by an …