Surface chemical reactions on self-assembled silane based monolayers
L Wang, US Schubert, S Hoeppener - Chemical Society Reviews, 2021 - pubs.rsc.org
In this review, we aim to update our review “Chemical modification of self-assembled silane-
based monolayers by surface reactions” which was published in 2010 and has developed …
based monolayers by surface reactions” which was published in 2010 and has developed …
Functionalization of oxide-free silicon surfaces with redox-active assemblies
B Fabre - Chemical Reviews, 2016 - ACS Publications
This review provides a comprehensive survey of the derivatization of hydrogen-terminated,
oxide-free silicon surfaces with electroactive assemblies (from molecules to polymers) …
oxide-free silicon surfaces with electroactive assemblies (from molecules to polymers) …
TEMPO monolayers on Si (100) electrodes: electrostatic effects by the electrolyte and semiconductor space-charge on the electroactivity of a persistent radical
This work demonstrates the effect of electrostatic interactions on the electroactivity of a
persistent organic free radical. This was achieved by chemisorption of molecules of 4-azido …
persistent organic free radical. This was achieved by chemisorption of molecules of 4-azido …
Light activated electrochemistry: light intensity and pH dependence on electrochemical performance of anthraquinone derivatized silicon
We seek to understand how the thermodynamics and kinetics of anthraquinone-containing
self-assembled monolayer on silicon electrodes are affected by two key experimental …
self-assembled monolayer on silicon electrodes are affected by two key experimental …
Electrochemical “switching” of Si (100) modular assemblies
We report on a modular approach for producing well-defined and electrochemically
switchable surfaces on Si (100). The switching of these surfaces is shown to change a Si …
switchable surfaces on Si (100). The switching of these surfaces is shown to change a Si …
Light-activated electrochemistry for the two-dimensional interrogation of electroactive regions on a monolithic surface with dramatically improved spatial resolution
The concept of light-activated electrochemistry (LAE) was recently presented where faradaic
electrochemistry could be spatially resolved on a monolithic silicon electrode by illuminating …
electrochemistry could be spatially resolved on a monolithic silicon electrode by illuminating …
Silicon Electrodes Functionalized with Perylene Bisimide π-Aggregates for Redox-Controlled Stabilization of Semiconducting Nanointerfaces
A Mukhopadhyay, K Liu, V Paulino… - ACS Applied Nano …, 2021 - ACS Publications
While the functionalization of silicon electrode surfaces with molecularly dissolved
chromophores paves the way to create diverse redox-responsive interfaces, leveraging …
chromophores paves the way to create diverse redox-responsive interfaces, leveraging …
Leveraging the assembly of a rylene dye to tune the semiconducting properties of functionalized n-Type, hybrid Si interfaces
A Mukhopadhyay, V Paulino, K Liu… - … applied materials & …, 2021 - ACS Publications
The functionalization of silicon electrodes with π-conjugated chromophores opens new
avenues to engineer hybrid semiconducting interfaces relevant to information storage and …
avenues to engineer hybrid semiconducting interfaces relevant to information storage and …
Molecular Strategies to Modulate the Electrochemical Properties of P-Type Si (111) Surfaces Covalently Functionalized with Ferrocene and Naphthalene Diimide
The surface coverage and molecular composition of redox-active molecules anchored on
conductive surfaces regulate the kinetic and thermodynamic parameters of charge transfer …
conductive surfaces regulate the kinetic and thermodynamic parameters of charge transfer …
The rapid formation of functional monolayers on silicon under mild conditions
We report on an exceedingly mild chemical functionalization of hydrogen-terminated Si
(100) with unactivated and unprotected bifunctional α, ω-dialkynes. Monolayer formation …
(100) with unactivated and unprotected bifunctional α, ω-dialkynes. Monolayer formation …