Photocrosslinkable natural polymers in tissue engineering

SH Moon, HJ Hwang, HR Jeon, SJ Park… - … in Bioengineering and …, 2023 - frontiersin.org
Natural polymers have been widely used in scaffolds for tissue engineering due to their
superior biocompatibility, biodegradability, and low cytotoxicity compared to synthetic …

Improving the Performance of Layer‐by‐Layer Processed Organic Solar Cells via Introducing a Wide‐Bandgap Dopant into the Upper Acceptor Layer

Q Chen, H Huang, D Hu, C Zhang, X Xu… - Advanced …, 2023 - Wiley Online Library
The layer‐by‐layer (LbL) solution‐processed organic solar cells (OSCs) are conductive to
achieve vertical phase separation, tunable donor–acceptor (D/A) interfaces, and favorable …

Design, Exploitation, and Rational Improvements of Diazirine-Based Universal Polymer Crosslinkers

ML Lepage, SF Musolino, JE Wulff - Accounts of Chemical …, 2024 - ACS Publications
Conspectus Addition of new covalent bonds between the chains of thermoplastic polymers
(ie, crosslinking) provides improved mechanical strength and enhanced high-temperature …

Solution-processable donor–π–acceptor type thieno [3, 2-b] thiophene derivatives; synthesis, photophysical properties and applications

R Isci, L Wan, S Topal, D Gunturkun… - Journal of Materials …, 2022 - pubs.rsc.org
Two novel donor-π-acceptor (D–π–A)-type pull–push materials, M1 and M2, having
triphenylamine as a donor and dimesitylboron as an acceptor, linked through a thieno [3, 2 …

Electronically optimized diazirine-based polymer crosslinkers

SF Musolino, M Mahbod, R Nazir, L Bi, HA Graham… - Polymer …, 2022 - pubs.rsc.org
Topical application of diazirine-based crosslinkers can upgrade the mechanical properties
of low-functionality commodity plastics by engaging in rapid C–H insertions along the …

Functionalization of Polydimethylsiloxane with Diazirine-Based Linkers for Covalent Protein Immobilization

J Li, L Bi, SF Musolino, JE Wulff… - ACS Applied Materials & …, 2023 - ACS Publications
Biomolecule attachment to solid supports is critical for biomedical devices, such as
biosensors and implants. Polydimethylsiloxane (PDMS) is commonly used for these …

Polyamine–diazirine conjugates for use as primers in UHMWPE–epoxy composite materials

R Nazir, L Bi, SF Musolino, OH Margoto… - ACS Applied Polymer …, 2022 - ACS Publications
Ultra-high-molecular weight polyethylene (UHMWPE) fibers show promise for use in fiber-
reinforced polymer composites but have poor interfacial adhesion to the epoxy resin that …

Efficient Cross-Linking through C–H Bond Insertion of Unfunctionalized Commodity Materials Using Diazirine-Containing Polymers

M Xu, B Huang, HK Beech, PT Getty… - ACS Macro …, 2024 - ACS Publications
The synthesis and application of multifunctional diazirine-containing polymers for on-
demand cross-linking of unfunctionalized commodity polymers through C–H bond insertion …

Synthesis and Reactivity of Diazirine-Containing Polymers via Controlled Radical Polymerization

B Huang, M Xu, CJ Hawker - Macromolecules, 2024 - ACS Publications
The synthesis and application of multifunctional diazirines as efficient precursors for the on-
demand generation of carbenes is demonstrated. While small-molecule multifunctional …

Crosslinking Vinyl‐Addition Polynorbornenes via Difunctional Diazirines to Generate Low Dielectric‐Constant and Low Dielectric‐Loss Thermosets

P Kandanarachchi, GA Meyer… - Macromolecular …, 2024 - Wiley Online Library
Thermosets having low dielectric constant (Dk< 3) and low dielectric dissipation factor (Df<
0.003), high glass transition temperature (Tg> 150° C), and good adhesion to copper are …