Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …

Conspectus Asymmetric functionalization of inert C–H bonds is undoubtedly a synthetically
significant yet challenging bond-forming process, allowing for the preparation of densely …

Allylic amines are valuable synthetic targets en route to diverse biologically active amine
products. Current allylic C–H amination strategies remain limited with respect to the viable N …

We describe a hybrid system that realizes cooperativity between an organophotoredox
acridinium catalyst and a chiral chromium complex catalyst, thereby enabling …

Nitrogen-containing compounds are the most common structural architectures in drug
candidates, natural and biological products, and small-molecule therapeutics. Within the …

We report details of the reaction mechanism for a coupling reaction of 1, 3-dienes with C-
nucleophiles that was catalyzed by a Ni/Cu cooperative catalyst system using Ni (cod) 2 and …

A highly enantioselective allylic C–H alkylation reaction of allylarenes with pyrazol-5-ones
has been established by the cooperative catalysis of a chiral palladium complex and chiral …

Direct coupling of unactivated olefins with primary alkylamines is considered to be an
efficient but unknown method for the construction of complex amines. Herein we report a …

Propylene gas is produced worldwide by steam cracking on million‐metric‐ton scale per
year. It serves as a valuable starting material for π‐bond functionalization but is rarely …

In recent years, transition metal-catalyzed C (sp 3) single bondH functionalization has
gradually emerged as a practical and powerful tool to prepare highly valuable chemicals. In …