Heteroatom-based diradical (oid) s
Heteroatom-centered diradical (oid) s have been in the focus of molecular main group
chemistry for nearly 30 years. During this time, the diradical concept has evolved and the …
chemistry for nearly 30 years. During this time, the diradical concept has evolved and the …
Recent advances in the chemistry of isolable carbene analogues with group 13–15 elements
Carbenes (R2C:), compounds with a divalent carbon atom containing only six valence shell
electrons, have evolved into a broader class with the replacement of the carbene carbon or …
electrons, have evolved into a broader class with the replacement of the carbene carbon or …
Room temperature intermolecular dearomatization of arenes by an acyclic iminosilylene
H Zhu, A Kostenko, D Franz, F Hanusch… - Journal of the American …, 2023 - ACS Publications
A novel nontransient acyclic iminosilylene (1), bearing a bulky super silyl group (− Si t Bu3)
and N-heterocyclic imine ligand with a methylated backbone, was prepared and isolated …
and N-heterocyclic imine ligand with a methylated backbone, was prepared and isolated …
Boryl-substituted low-valent heavy group 14 compounds
C Duan, C Cui - Chemical Society Reviews, 2024 - pubs.rsc.org
Low valent group 14 compounds exhibit diverse structures and reactivities. The employment
of diazaborolyl anions (NHB anions), isoelectronic analogues to N-heterocyclic carbenes …
of diazaborolyl anions (NHB anions), isoelectronic analogues to N-heterocyclic carbenes …
Fast and scalable solvent-free access to Lappert's heavier tetrylenes E {N (SiMe 3) 2} 2 (E= Ge, Sn, Pb) and ECl {N (SiMe 3) 2}(E= Ge, Sn)
Iconic Lappert's heavier tetrylenes E {N (SiMe3) 2} 2 (E= Ge (1), Sn (2), Pb (3)) have been
efficiently prepared from GeCl2·(1, 4-dioxane), SnCl2 or PbCl2 and Li {N (SiMe3) 2} via a …
efficiently prepared from GeCl2·(1, 4-dioxane), SnCl2 or PbCl2 and Li {N (SiMe3) 2} via a …
Synthesis and Reactivity of Base-Stabilized and Base-Free Silaimidoyl Bromides
P Hädinger, MP Müller, A Hinz - Inorganic Chemistry, 2024 - ACS Publications
The reactivity of the base-free bromosilylene dtbpCbzSiBr (dtbpCbz= 1, 8-bis (3, 5-di-tert-
butylphenyl)-3, 6-di-tert-butylcarbazolyl) toward carbodiimides and azides was studied in …
butylphenyl)-3, 6-di-tert-butylcarbazolyl) toward carbodiimides and azides was studied in …
Bis‐Silylene‐Supported Aluminium Atoms with Aluminylene and Alane Character
The suitability of electron‐rich bis‐silylenes, specifically the neutral chelating [SiII (Xant) SiII]
ligand (SiII= PhC (NtBu) 2Si, Xant= 9, 9‐dimethylxanthene) and the anionic [SiII (NAcrid) …
ligand (SiII= PhC (NtBu) 2Si, Xant= 9, 9‐dimethylxanthene) and the anionic [SiII (NAcrid) …
Synthesis and Some Coordination Chemistry of Phosphane-Difunctionalized Bis (amidinato)-Heavier Tetrylenes: A Previously Unknown Class of PEP Tetrylenes (E …
The bis (amidinato)-heavier tetrylenes E (bzamP) 2 (E= Ge (2a) and Sn (2b); bzamP= N-
isopropyl-N′-(diphenylphosphanylethyl) benzamidinate), which are equipped with one …
isopropyl-N′-(diphenylphosphanylethyl) benzamidinate), which are equipped with one …
Synthesis, Characterization and Reactivity of a σ‐Donating Ni0‐Stabilized Silyliumylidene Ion
S Takahashi, M Frutos, A Baceiredo… - Angewandte Chemie …, 2022 - Wiley Online Library
The synthesis of a silyliumylidene cation complex 2 stabilized by a Ni0‐based donating
ligand is reported. Experimental and theoretical studies demonstrate that the highly …
ligand is reported. Experimental and theoretical studies demonstrate that the highly …
Reactivity of a Strictly T‐Shaped Phosphine Ligated by an Acridane Derived NNN Pincer Ligand
AJ King, J Abbenseth… - Chemistry–A European …, 2023 - Wiley Online Library
The steric tuning of a tridentate acridane‐derived NNN pincer ligand allows for the isolation
of a strictly T‐shaped phosphine that exhibits ambiphilic reactivity. Well‐defined phosphorus …
of a strictly T‐shaped phosphine that exhibits ambiphilic reactivity. Well‐defined phosphorus …