A cyclic alkyl (amino) carbene (CAAC)-stabilized 1, 4-diborabenzene (DBB, 1) reacts with
the group 10 precursor [Ni (CO) 4] to yield the DBB pogo-stick complex [(η6-DBB) Ni …

Structural, electronic and magnetic properties of small bimetallic zirconium–palladium
clusters, Zr n Pd m (n+ m⩽ 5), have been investigated using density functional theory with …

Ferrocenyl diphosphine containing iron–palladium clusters [(CO) 6Fe2 (μ3-Y) 2Pd {PPh2
(η5-C5H4) Fe (η5-C5H4) PPh2})](Y= Se (9); Y= Te (10)) have been prepared by the room …

Room temperature stirring of THF solution of [Fe3Se2 (CO) 9] and P (C2R) 3 (R= Ph, Fc), in
presence of Me3NO· 2H2O, yield monosubstituted [Fe3Se2 (CO) 8 {P (C2R) 3}](1, R= Ph; 2 …

A series of critical reviews and perspectives focussing on specific aspects of organometallic
chemistry interfacing with other fields of study are provided. For this volume, the critical …

The reaction of [Fe3 (CO) 12] with bis [2‐(diphenylphosphino) phenyl] ether (DPEphos) in
refluxing THF afforded a mononuclear complex,[Fe (CO) 4 (η1‐P‐DPEphos)](1), as major …

Recently, we have developed several synthetic routes to a series of chalcogen‐containing
group 6 (emphasizing on chromium) carbonyl clusters, in which the interesting structural …

Abstract Structures of Fe 3 Pt 3 (CO) 15 (1), Fe 2 Pt 5 (CO) 12 (COD) 2 (2), Fe 2 Pt (CO) 8
(COD)(3) and Fe 2 Pt 2 (CO) 10 (4), as well as the driving forces for their formation from Fe …

The formation of aryl–aryl bonds is an important transformation in organic chemistry. The
moiety is commonly found in pharmaceutically relevant compounds as well as in advanced …

The coordination chemistry of large-bite-angle diphosphine ligands has received
considerable attention in organometallic chemistry because of their potential utility as …