Herbicidal ionic liquids: A promising future for old herbicides? Review on synthesis, toxicity, biodegradation, and efficacy studies

W Wilms, M Woźniak-Karczewska… - Journal of agricultural …, 2020 - ACS Publications
The transformation of agrochemicals into herbicidal ionic liquids (HILs) has been suggested
as a solution to problems associated with commercial forms of herbicides. The aim of this …

Effect of cation sorption on 2, 4-D mobility of herbicidal ionic liquids in agricultural soil combined with diversity of the bacterial community

M Woźniak-Karczewska, A Parus… - ACS Sustainable …, 2022 - ACS Publications
Ionic liquids (ILs) are thought to have unlimited configurability of the properties through
selection of ions, eg, thermal stability, nonflammability, and lower toxicity. For the example of …

[HTML][HTML] Biodegradable amidequats, derivatives of caprylic and pelargonic acids as cationic surfactants for agricultural applications

A Syguda, Ł Ławniczak, P Wróbel, F Walkiewicz… - Journal of Molecular …, 2023 - Elsevier
In this study, we proposed to incorporate natural herbicides ie caprylic and pelargonic acids
into an amide functional group of a cationic surfactant, thus obtaining amidequats. All the …

[HTML][HTML] Surface activity and phytotoxicity of morpholinium herbicidal ionic liquids

M Wojcieszak, B Krupa, A Syguda, F Walkiewicz… - Journal of Molecular …, 2022 - Elsevier
The use of efficient synthesis methods to obtain novel herbicidal ionic liquids (HILs) with
biological activity is extremely important because it can eliminate certain negative …

Can ionic liquids exist in the soil environment? Effect of quaternary ammonium cations on glyphosate sorption, mobility and toxicity in the selected herbicidal ionic …

A Parus, O Zdebelak, T Ciesielski, R Szumski… - Journal of Molecular …, 2023 - Elsevier
Ionic liquids (ILs) are described as low-impact green chemicals in which the cation can
influence the properties of the anion through ion pair formation. We decided to see how …

2, 4-D versus 2, 4-D based ionic liquids: Effect of cation on herbicide biodegradation, tfdA genes abundance and microbiome changes during soil bioaugmentation.

W Wilms, M Woźniak-Karczewska, M Niemczak… - Journal of Hazardous …, 2023 - Elsevier
The commercial formulations of herbicides rely on surfactants which increase the efficiency
of active substance. Herbicidal ionic liquids (ILs), in which cationic surfactants are combined …

Double-action herbicidal ionic liquids based on dicamba esterquats with 4-CPA, 2, 4-D, MCPA, MCPP, and clopyralid anions

A Syguda, M Wojcieszak, K Materna… - ACS Sustainable …, 2020 - ACS Publications
Herbicides such as (3, 6-dichloro-2-methoxy) benzoic acid (dicamba),(4-chloro-2-
methylphenoxy) acetic acid (MCPA),(2, 4-dichlorophenoxy) acetic acid (2, 4-D), or (±)-2-(4 …

Glyphosate versus glyphosate based ionic liquids: Effect of cation on glyphosate biodegradation, soxA and phnJ genes abundance and microbial populations …

W Wilms, A Parus, J Homa, M Batycka, M Niemczak… - Chemosphere, 2023 - Elsevier
The applicability of herbicidal ionic liquids (HILs) as an alternative form of herbicides is
currently evaluated. Yet, the available research is lacking information on the behaviour of …

Glycine betaine-based ionic liquids and their influence on bacteria, fungi, insects and plants

DK Kaczmarek, D Gwiazdowska, K Juś… - New Journal of …, 2021 - pubs.rsc.org
A new group of bioinspired ionic liquids (ILs) based on glycine betaine and natural or
synthetic anions was synthesized. The developed synthesis methods enabled the …

Ecotoxicity studies reveal that organic cations in dicamba-derived ionic liquids can pose a greater environmental risk than the herbicide itself

J Homa, W Stachowiak, A Olejniczak… - Science of The Total …, 2024 - Elsevier
The following research provides novel and relevant insights into potential environmental
consequences of combination of various organic cations with commercial systemic herbicide …