The selective functionalization of alkanes has long been recognized as a prominent
challenge and an arduous task in organic synthesis. Hydrogen atom transfer (HAT) …

The functionalisation of C–H bonds has been an enormous achievement in synthetic
methodology, enabling new retrosynthetic disconnections and affording simple synthetic …

The intermediacy of alkoxy radicals in cerium-catalyzed C–H functionalization via H-atom
abstraction has been unambiguously confirmed. Catalytically relevant Ce (IV)–alkoxide …

Selective functional group interconversions in complex molecular settings underpin many of
the challenges facing modern organic synthesis. Currently, a privileged subset of functional …

The cross-dehydrogenative coupling (CDC) reaction is the most direct and efficient method
for constructing α-tertiary amino acids (ATAAs), which avoids the pre-activation of C (sp3)-H …

A nickel‐catalyzed reductive cross‐electrophile coupling between the redox‐active N‐
trifluoroethoxyphthalimide and iodoarenes is documented. The protocol reproduces a formal …

We highlight key contributions in the field of direct radical CAr− H (hetero) aromatic
functionalization involving fluorinated radicals. A compilation of Functional Group Transfer …

Rate constants for hydrogen atom transfer (HAT) reactions of substituted toluenes with tert-
butyl, tert-butoxy, and tert-butylperoxyl radicals are reanalyzed here using the free energies …

The influence of steric effects on the rates of hydrogen atom transfer (HAT) reactions
between oxyradicals and alkanes is explored computationally. Quantum chemical density …

Cost-effective metal trihalides exhibiting high specific capacity hold significant promise as
anodes in lithium-ion batteries (LIBs). Within this study, the spotlight falls on innovative …